TEST BANK for Organic Chemistry 6th Edition
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Smith / All Chapters 1 - 29 / Full Complete
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Page 1
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,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter 21
IIll Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22
IIll Carbonyl Condensation Reactions
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Chapter 23
IIll Amines
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Chapter 24
IIll Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25
IIll Pericyclic Reactions
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Chapter 26
IIll Carbohydrates
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Chapter 27
IIll Amino Acids and Proteins
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Chapter 28
IIll Synthetic Polymers
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Chapter 29
IIll Lipids (Available online)
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Page 2 IIll
, Chapter 1: Structure and Bonding IIll IIll IIll IIll
1. What is the ground-state electronic configuration of a carbon
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atom? A) 1s2, 2s2, 2p5
IIll IIll B) 1s2, 2s2, 2p2 C) 1s2,
I I l l IIll IIll I I l l IIll IIll I I l l
2s2, 2p6
IIll IIll D) 1s2, 2s2, 2p4 I I l l IIll IIll
2. What is the ground-state electronic configuration of a fluorine
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atom? A) 1s2, 2s2, 2p2
IIll Il B) 1s2, 2s2, 2p3 C) 1s2,
I I l l IIll IIll I I l l IIll IIll I I l l
2s2, 2p4
IIll IIll D) 1s2, 2s2, 2p5 I I l l IIll IIll
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)? A)
IIll Il 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, IIll IIll IIll IIll
3s2
IIll
B) 1s2, 2s2, 2p6, 3s1 IIll IIll IIll D) 1s2, 2s2, 2p6, 3s2, 3p2 IIll IIll IIll IIll
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
Il IIll C) 1s2, 2s2, 2p6, 3s2, 3p5
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B) 1s2, 2s2, 2p6, 3s2, 3p6IIll IIll IIll IIll D) 1s2, 2s2, 2p6, 3s2, 3p4 IIll IIll IIll IIll
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons. IIll IIll IIll IIll IIll IIll
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and IIll IIll IIll
Bonding
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C) They are the outermost electrons.IIll IIll IIll IIll
D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals. IIll IIll IIll IIll IIll IIll IIll IIll IIll IIll
7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl I I l l I I l l I I l l
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO I I l l I I l l I I l l
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B) IIll I I l l I, IV IIll C) I I l l II, III IIll D) II, IV IIll IIll
10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
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A) I > II > III > IV
IIll IIll IIll IIll IIll IIll C) IV > III > II > I IIll IIll IIll IIll IIll IIll
B) IV > II > I > III IIll IIll IIll IIll IIll IIll D) IV > II > III > I IIll IIll IIll IIll IIll IIll
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms 3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms 2 covalent bonds.
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Page 4 IIll
IIll IIll IIll IIll IIll IIll
Smith / All Chapters 1 - 29 / Full Complete
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Page 1
IIll
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter 21
IIll Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22
IIll Carbonyl Condensation Reactions
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Chapter 23
IIll Amines
IIll
Chapter 24
IIll Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25
IIll Pericyclic Reactions
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Chapter 26
IIll Carbohydrates
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Chapter 27
IIll Amino Acids and Proteins
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Chapter 28
IIll Synthetic Polymers
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Chapter 29
IIll Lipids (Available online)
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Page 2 IIll
, Chapter 1: Structure and Bonding IIll IIll IIll IIll
1. What is the ground-state electronic configuration of a carbon
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atom? A) 1s2, 2s2, 2p5
IIll IIll B) 1s2, 2s2, 2p2 C) 1s2,
I I l l IIll IIll I I l l IIll IIll I I l l
2s2, 2p6
IIll IIll D) 1s2, 2s2, 2p4 I I l l IIll IIll
2. What is the ground-state electronic configuration of a fluorine
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atom? A) 1s2, 2s2, 2p2
IIll Il B) 1s2, 2s2, 2p3 C) 1s2,
I I l l IIll IIll I I l l IIll IIll I I l l
2s2, 2p4
IIll IIll D) 1s2, 2s2, 2p5 I I l l IIll IIll
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)? A)
IIll Il 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, IIll IIll IIll IIll
3s2
IIll
B) 1s2, 2s2, 2p6, 3s1 IIll IIll IIll D) 1s2, 2s2, 2p6, 3s2, 3p2 IIll IIll IIll IIll
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
Il IIll C) 1s2, 2s2, 2p6, 3s2, 3p5
IIll IIll IIll IIll IIll
B) 1s2, 2s2, 2p6, 3s2, 3p6IIll IIll IIll IIll D) 1s2, 2s2, 2p6, 3s2, 3p4 IIll IIll IIll IIll
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons. IIll IIll IIll IIll IIll IIll
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and IIll IIll IIll
Bonding
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C) They are the outermost electrons.IIll IIll IIll IIll
D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals. IIll IIll IIll IIll IIll IIll IIll IIll IIll IIll
7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl I I l l I I l l I I l l
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO I I l l I I l l I I l l
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B) IIll I I l l I, IV IIll C) I I l l II, III IIll D) II, IV IIll IIll
10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
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A) I > II > III > IV
IIll IIll IIll IIll IIll IIll C) IV > III > II > I IIll IIll IIll IIll IIll IIll
B) IV > II > I > III IIll IIll IIll IIll IIll IIll D) IV > II > III > I IIll IIll IIll IIll IIll IIll
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms 3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms 2 covalent bonds.
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