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Summary

Summary - Unit 9 - Kinetics I

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KINETICS

CATALYSTS ↳


save

save
money

energy

eg zeolite :
largeS A




A substance that by
increases the rate of reaction
providing
an alterative that has lower activation
pathway a energy
.

It is
chemically unchanged at the end of the reaction
.
bond with the active sites on me

surface of the catalyst
/
W

substances adsorb to the surface desorption -
molec
Catalyst in a different statel >
- -
=
HETEROGENEOUS-phase from the reactants of solid heterogeneous catalysts reaction
from the surface
lowers activation occurs
Soli
aest energy
have
so more particles

enough energy
e
.
g N2(g) + 34 =(g) >
-
2NHz (g) potential




*
.


M
energy


4 SA of Catalyst =
↑rate of reaction
reactants




H OMOGENEOUS-reactants
catalyst in the same phase as the
- products




S

progress

aqueous
-
>
generally in aqueous reactants
-



combine
reformed
form intermediate species :
reactants catalyst ->
products +
catalyst
2nd bump-

Y energy required
to


break up intermediast
internedes
a




USES OF CATALUSTS




INDUSTRY : ENVIROMENTALLY :
↑ pressure ↑rate molecules per unit
CO2/ CO2/
↳ lower ↳
temp-less money lower temp/pressure required -

less energy
better atom
↳ ↳ less
speeds reaction waste produced-economies CATALYTIC CONVERTERS -


reduce levels of pollut
made of rhodium , platinum and palladium alloy

changes properties of products 200 + 2 >
2CO2 + N




MAXWELL-BOLTIM
Conc . or volume of ractant/product made

RATE OF REACTION unit time




HOW MSUR
I snowing energy in
gas particles
measure mass lost



HOW LONG IT TAKES
use a fine cupboard
any namful/toxic 10 of 1
likely
for ·




gas Molecules most
- energy of a
particle
O




M
in a sample
ELECTICAL


conductiveenvit

VOLUME OF GAS ·


mean energy of
PRODUCED Syringe ↳
particles

IN-H t
to get +he if Ations are o
used up
>



Po
- conc
produced
TITRATION -
CHANGE being
a H+ H
+

area total 10
PH pH will change -




under = of Molecules

↓ sech ladd uchencas
curve in sample

ac
absorbance/conc

-
COLORIMETRY - graph
12 + CH3(OCH >
- (MyCoc42 +
1- + H
+

=
-
brown colourless colourless L


W

O starts at 0, 0

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