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Summary OCR (A) A level Periodic Table and Energy Spec Notes

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OCR
Module
Unit 3

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Periodic Table and Energy
PERIODICITY : 3.1.1

Periodic trend in electron configuration across period 2 and 3

Period 2 has only two outer shells

Period 3 has three outer shells

Period 3 has larger atomic radius therefore it is less reactive as it will
require more energy to gain an electron as the electrostatic forces of
attraction is weaker

where is the s block

Group 1 and Group 2

Including helium

where is the p block

Group 3 , 4 , 5 , 6 , 7 and 0

where is the d block

Transition metals

what is first ionisation energy

Amount of energy required to remove 1 mol of electrons from 1 mole of
gaseous atoms to form one mole of 1+ ions

what is the trend of first ionisation energy across periods

Across a period the shielding remains the same so it doesn't effect it

The nuclear charge increases as the proton number increases

Therefore there is stronger electrostatic forces of attraction across a period

Stronger electrostatic forces means smaller atomic radius as you go across
as outer electrons are more attracted to the nucleus and pulled in closer

Therefore the ionisation energy increases as you go across the period




Periodic Table and Energy 1

, what is the trend of first ionisation energy down groups

As you go down the shielding increases as there are more electron shells

The atomic radius increases and nuclear charge increases

Ionisation energy decreases as you go down the group

why is there a change in trend from O to N

O has a pair of opposite spin electrons in the first p orbital that will repel
each other and thus require less energy so the first ionisation enrgy would
be lower than N instead of higher

N electron configuration = 1s2 2s2 2p3

O electron configuration = 1s2 2s2 2p4

why is there a change in trend from B to Be

Ionisation energy in boron is lower

Boron has an unpaired electron in one 2p orbital which is a higher energy
level

Easier to remove electron from higher energy level when the elctron is
unpaired therefore less energy is required

Be electron configuration = 1s2 2s2

B electron configuration = 1s2 2s2 2p1

what is second ionisation energy

energy required to remove one mole of electrons from one mole of 1+
gaseous ions to form one mole of 2+ gaseous ions

what is the trend of melting and boiling point across period 3

the melting point increases from Group 1 to Group 3 because they are
metallic lattices

Decrease from group 4 to group 5 due to change from giant covalent
structure (Si) to simple covalent molecule (P)

(P) forms P4 molecules which is very small so the london forces are very
weak so less energy needed than Sulphur



Periodic Table and Energy 2

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