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AP CHEMISTRY ALL UNITS REVIEW AND SOLUTION GUIDE WITH CERTIFIED CONTENT FOR .

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covalent bonds - Answer: bond in which two atoms share electrons; each atom counts the e- as a part of its valence shell single bonds - Answer: one sigma bond, one e- pair; longest bond, least energy double bonds - Answer: one sigma bond, one pi bond; two e- pairs triple bonds - Answer: one sigma bond, two pi bonds; 3 e- pairs; shortest bond, most energy network covalent bonds - Answer: lattice of covalent bonds; network solid (acts similar to one molecule); very hard, high melting/boiling points; poor conductors the common network solids - Answer: SiO2, doping - Answer: the addition of an impurity to an existing lattice p-doping - Answer: create a hole (positively charged) that draws electrons through the substance (add a substance with one LESS valence e-) i.e. si + al n-doping - Answer: add a substance with one MORE valence e- which leaves a free e- to travel freely i.e. si + p polarity - Answer: exists when a molecule has a clustering of negative charge on one side due to unequal sharing of electrons (e- are pulled to the more electronegative side); creates dipoles in molecules dipole moment - Answer: the measurement of the polarity of a molecule; the unit of measurement is a debye (D) more polar molecule.... - Answer: .... larger dipole moment intermolecular forces (IMFs) - Answer: forces that exist between molecules in a covalently bonded substance; not bonds dipole-dipole forces - Answer: the positive end of one polar molecule is attracted to the negative end of another molecule; relatively weak attraction force hydrogen bonding - Answer: strong IMF between two moelcules; F, O, N; have higher melting and boiling points than molecules with other IMFs london dispersion forces - Answer: IMFs that occur between all molecules; occur because of the random motions of electrons on atoms within molecules to create instantaneous polarities; molecules with more e- will have greater _________________ forces substances with only london dispersion forces usually... - Answer: ... are gases at room temp, and boil/melt at extremely low temps melting & boiling points of a covalent substance is almost always _____________ than that of ionic substances - Answer: lower vapor pressure - Answer: the pressure exerted by a vapor over a liquid resonance structures - Answer: structures that occur when it is possible to draw two or more valid lewis electron dot diagrams that have the same number of electron pairs for a molecule or ion formal charge - Answer: used to find which structure is most likely to occur; valence - assigned

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AP CHEMISTRY ALL UNITS REVIEW AND
SOLUTION GUIDE WITH CERTIFIED
CONTENT FOR 2025 2026.
🔘distillation - Answer: the process that separates the substances in a solution based on their
boiling points

🔘precipitation reaction - Answer: a reaction in which an insoluble substance (salt) forms and
separates from the solution

🔘net ionic equation - Answer: an equation for a reaction in solution showing only those
particles that are directly involved in the chemical change

🔘limiting reactant - Answer: the substance that controls the quantity of product that can form
in a chemical reaction; moles of each reactant divided by moles used in reaction

🔘gravimetric analysis - Answer: a type of quantitative analysis in which the amount of a
species in a material is determined by converting the species to a precipitate that can be
isolated completely and weighed

🔘empirical formula - Answer: simplest ratio of the molecules making up a compound

🔘molecular formula - Answer: actual formula for a substance

🔘coulombs law - Answer: the amount of energy that an electron has depends on its distance
from the nucleus of an atom; e=k(q1*q20)/r

🔘ionization energy - Answer: amount of energy necessary to remove electrons from an atom
(electromagnetic energy exceeds binding energy)

🔘shielding electrons - Answer: electrons between a valence electron and the nucleus that
decreases the attraction between the nucleus and the valence electron

🔘periodic trend: left to right - Answer: periodic trend: atomic radius decreases; protons are
added to the nucleus so valence electrons are more strongly attracted

ionization energy increases (protons are added to the nucleus)

🔘periodic trend: down a group - Answer: periodic trend: atomic radius increases; shells of
electrons are added which shield the more distant shells and valence e- get farther away

, ionization energy decreases (shells of e- added, each inner shell shields more and reduces the
pull on valence e- so they are easier to remove)

🔘ionic bond - Answer: bond between metal and nonmetal; electrons are NOT shared: the
cation gives an e- up to the anion

🔘metallic bonding - Answer: bond between two metals; sea of electrons that make metals
such good conductors; delocalized structure allows for malleability and ductility

🔘interstitial alloy - Answer: metal atoms with vastly different radii combine; ex. steel

🔘substitutional alloy - Answer: metal atoms with similar radii combine; ex. brass

🔘covalent bonds - Answer: bond in which two atoms share electrons; each atom counts the
e- as a part of its valence shell

🔘single bonds - Answer: one sigma bond, one e- pair; longest bond, least energy

🔘double bonds - Answer: one sigma bond, one pi bond; two e- pairs

🔘triple bonds - Answer: one sigma bond, two pi bonds; 3 e- pairs; shortest bond, most
energy

🔘network covalent bonds - Answer: lattice of covalent bonds; network solid (acts similar to
one molecule); very hard, high melting/boiling points; poor conductors

🔘the common network solids - Answer: SiO2,

🔘doping - Answer: the addition of an impurity to an existing lattice

🔘p-doping - Answer: create a hole (positively charged) that draws electrons through the
substance (add a substance with one LESS valence e-) i.e. si + al

🔘n-doping - Answer: add a substance with one MORE valence e- which leaves a free e- to
travel freely
i.e. si + p

🔘polarity - Answer: exists when a molecule has a clustering of negative charge on one side
due to unequal sharing of electrons (e- are pulled to the more electronegative side); creates
dipoles in molecules
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