TEST BANK for Organic Chemistry 6th Edition
5 5 5 5 5 5
Smith / All Chapters 1 - 29 / Full Complete
5 5 5 5 5 5 5 5 5 5
Page 51
,Chapter 1 Structure and Bonding
5 5 5 5
Chapter 2 Acids and Bases
5 5 5 5
Chapter 3 Introduction to Organic Molecules and Functional Groups
5 5 5 5 5 5 5 5
Chapter 4 Alkanes
5 5
Chapter 5 Stereochemistry
5 5
Chapter 6 Understanding Organic Reactions
5 5 5 5
Chapter 7 Alkyl Halides and Nucleophilic Substitution
5 5 5 5 5 5
Chapter 8 Alkyl Halides and Elimination Reactions
5 5 5 5 5 5
Chapter 9 Alcohols, Ethers, and Related Compounds
5 5 5 5 5 5
Chapter 10 Alkenes and Addition Reactions
5 5 5 5 5
Chapter 11 Alkynes and Synthesis
5 5 5 5
Chapter 12 Oxidation and Reduction
5 5 5 5
Spectroscopy A Mass Spectrometry
5 5 5
Spectroscopy B Infrared Spectroscopy
5 5 5
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
5 5 5 5 5
Chapter 13 Radical Reactions
5 5 5
Chapter 14 Conjugation, Resonance, and Dienes
5 5 5 5 5
Chapter 15 Benzene and Aromatic Compounds
5 5 5 5 5
Chapter 16 Reactions of Aromatic Compounds
5 5 5 5 5
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
5 5 5 5 5 5 5
Oxidation and Reduction
5 5 5
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
5 5 5 5 5
Chapter 19 Carboxylic Acids and Nitriles
5 5 5 5 5
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
5 5 5 5 5 5 5 5
Substitution
5
Chapter 21
5 Substitution Reactions of Carbonyl Compounds at the α-Carbon
5 5 5 5 5 5 5 5
Chapter 22
5 Carbonyl Condensation Reactions
5 5 5
Chapter 23
5 Amines
5
Chapter 24
5 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
5 5 5 5 5 5
Chapter 25
5 Pericyclic Reactions
5 5
Chapter 26
5 Carbohydrates
5
Chapter 27
5 Amino Acids and Proteins
5 5 5 5
Chapter 28
5 Synthetic Polymers
5 5
Chapter 29
5 Lipids (Available online)
5 5 5
Page 52
, Chapter 1: Structure and Bonding
5 5 5 5
1. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5carbon
2 2 5
5atom? 5A) 5 1s , 52s , 52p B) 5 1s2, 52s2, 52p2 C) 5 1s2, 52s2,
6 2 2 4
52p D) 5 1s , 52s , 52p
2. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5fluorine
A) 5 1s2, 52s2, 52p2
5atom?5 B) 5 1s2, 52s2, 52p3 C) 5 1s2, 52s2,
4
52p D) 5 1s2, 52s2, 52p5
3. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5magnesium 5cation
2+
5(Mg )?5A) 1s2, 52s2, 52p6 C) 1s2, 52s2,
6 2
52p , 53s
B) 1s2, 52s2, 52p6, 53s1 D) 1s2, 52s2, 52p6, 53s2, 53p2
4. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5chlorine 5anion
—
5(Cl )?5A) 1s2, 52s2, 52p6 C)
1s2, 52s2, 52p6, 53s2, 53p5
B) 1s2, 52s2, 52p6, 53s2, 53p6 D) 1s2, 52s2, 52p6, 53s2, 53p4
5. Which 5of 5the 5following 5statements 5about 5valence 5electrons 5is 5true?
A) They 5are 5the 5most 5tightly 5held 5electrons.
B) They 5do 5not 5participate 5in 5chemical 5reactions.
Page 53
, Chapter 51: 5Structure 5and
5Bonding
C) They 5are 5the 5outermost 5electrons.
D) They 5reveal 5the 5period 5number 5of 5a 5second-row 5element.
6. Which 5of 5the 5following 5statements 5about 5bonding 5is 5true?
A) Covalent 5bonds 5result 5from 5the 5transfer 5of 5electrons 5from 5one 5element 5to 5another.
B) Ionic 5bonds 5result 5from 5the 5transfer 5of 5electrons 5from 5a 5metal 5to 5a 5non-metal.
C) Ionic 5bonds 5result 5from 5the 5sharing 5of 5electrons 5between 5two 5non-metals.
D) Covalent 5bonds 5result 5from 5the 5sharing 5of 5electrons 5between 5two 5metals.
7. Which 5of 5the 5following 5would 5you 5expect 5to 5have 5ionic 5bonds?
A) CO B) 5 FBr C) 5 NF3 D) 5 NaCl
8. Which 5of 5the 5following 5molecules 5has 5nonpolar 5covalent 5bonds?
A) HCl B) 5 N2 C) 5 CHCl3 D) 5 NO
9. Which 5of 5the 5following 5molecules 5contain 5both 5covalent 5and 5ionic 5bonds?
A) I, 5II B) 5 I, 5IV C) 5 II, 5III D) 5II, 5IV
10. Arrange 5the 5following 5bonds 5in 5decreasing 5order 5of 5ionic 5character, 5putting 5the
5most5
ionic 5first.
A) I 5> 5II 5> 5III 5> 5IV C) IV 5> 5III 5> 5II 5> 5I
B) IV 5> 5II 5> 5I 5> 5III D) IV 5> 5II 5> 5III 5> 5I
11. Which 5of 5the 5following 5statements 5correctly 5describes 5the 5typical 5number 5of
5bonds 5for5
carbon, 5nitrogen, 5and 5oxygen 5in 5most 5neutral 5organic 5molecules?
A) Carbon 5forms 54 5covalent 5bonds, 5nitrogen 5forms 52 5covalent 5bonds 5and 5oxygen
5forms5 3 5covalent 5bonds.
B) Carbon 5forms 54 5covalent 5bonds, 5nitrogen 5forms 53 5covalent 5bonds 5and 5oxygen
5forms5 2 5covalent 5bonds.
Page 54
5 5 5 5 5 5
Smith / All Chapters 1 - 29 / Full Complete
5 5 5 5 5 5 5 5 5 5
Page 51
,Chapter 1 Structure and Bonding
5 5 5 5
Chapter 2 Acids and Bases
5 5 5 5
Chapter 3 Introduction to Organic Molecules and Functional Groups
5 5 5 5 5 5 5 5
Chapter 4 Alkanes
5 5
Chapter 5 Stereochemistry
5 5
Chapter 6 Understanding Organic Reactions
5 5 5 5
Chapter 7 Alkyl Halides and Nucleophilic Substitution
5 5 5 5 5 5
Chapter 8 Alkyl Halides and Elimination Reactions
5 5 5 5 5 5
Chapter 9 Alcohols, Ethers, and Related Compounds
5 5 5 5 5 5
Chapter 10 Alkenes and Addition Reactions
5 5 5 5 5
Chapter 11 Alkynes and Synthesis
5 5 5 5
Chapter 12 Oxidation and Reduction
5 5 5 5
Spectroscopy A Mass Spectrometry
5 5 5
Spectroscopy B Infrared Spectroscopy
5 5 5
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
5 5 5 5 5
Chapter 13 Radical Reactions
5 5 5
Chapter 14 Conjugation, Resonance, and Dienes
5 5 5 5 5
Chapter 15 Benzene and Aromatic Compounds
5 5 5 5 5
Chapter 16 Reactions of Aromatic Compounds
5 5 5 5 5
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
5 5 5 5 5 5 5
Oxidation and Reduction
5 5 5
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
5 5 5 5 5
Chapter 19 Carboxylic Acids and Nitriles
5 5 5 5 5
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
5 5 5 5 5 5 5 5
Substitution
5
Chapter 21
5 Substitution Reactions of Carbonyl Compounds at the α-Carbon
5 5 5 5 5 5 5 5
Chapter 22
5 Carbonyl Condensation Reactions
5 5 5
Chapter 23
5 Amines
5
Chapter 24
5 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
5 5 5 5 5 5
Chapter 25
5 Pericyclic Reactions
5 5
Chapter 26
5 Carbohydrates
5
Chapter 27
5 Amino Acids and Proteins
5 5 5 5
Chapter 28
5 Synthetic Polymers
5 5
Chapter 29
5 Lipids (Available online)
5 5 5
Page 52
, Chapter 1: Structure and Bonding
5 5 5 5
1. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5carbon
2 2 5
5atom? 5A) 5 1s , 52s , 52p B) 5 1s2, 52s2, 52p2 C) 5 1s2, 52s2,
6 2 2 4
52p D) 5 1s , 52s , 52p
2. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5fluorine
A) 5 1s2, 52s2, 52p2
5atom?5 B) 5 1s2, 52s2, 52p3 C) 5 1s2, 52s2,
4
52p D) 5 1s2, 52s2, 52p5
3. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5magnesium 5cation
2+
5(Mg )?5A) 1s2, 52s2, 52p6 C) 1s2, 52s2,
6 2
52p , 53s
B) 1s2, 52s2, 52p6, 53s1 D) 1s2, 52s2, 52p6, 53s2, 53p2
4. What 5is 5the 5ground-state 5electronic 5configuration 5of 5a 5chlorine 5anion
—
5(Cl )?5A) 1s2, 52s2, 52p6 C)
1s2, 52s2, 52p6, 53s2, 53p5
B) 1s2, 52s2, 52p6, 53s2, 53p6 D) 1s2, 52s2, 52p6, 53s2, 53p4
5. Which 5of 5the 5following 5statements 5about 5valence 5electrons 5is 5true?
A) They 5are 5the 5most 5tightly 5held 5electrons.
B) They 5do 5not 5participate 5in 5chemical 5reactions.
Page 53
, Chapter 51: 5Structure 5and
5Bonding
C) They 5are 5the 5outermost 5electrons.
D) They 5reveal 5the 5period 5number 5of 5a 5second-row 5element.
6. Which 5of 5the 5following 5statements 5about 5bonding 5is 5true?
A) Covalent 5bonds 5result 5from 5the 5transfer 5of 5electrons 5from 5one 5element 5to 5another.
B) Ionic 5bonds 5result 5from 5the 5transfer 5of 5electrons 5from 5a 5metal 5to 5a 5non-metal.
C) Ionic 5bonds 5result 5from 5the 5sharing 5of 5electrons 5between 5two 5non-metals.
D) Covalent 5bonds 5result 5from 5the 5sharing 5of 5electrons 5between 5two 5metals.
7. Which 5of 5the 5following 5would 5you 5expect 5to 5have 5ionic 5bonds?
A) CO B) 5 FBr C) 5 NF3 D) 5 NaCl
8. Which 5of 5the 5following 5molecules 5has 5nonpolar 5covalent 5bonds?
A) HCl B) 5 N2 C) 5 CHCl3 D) 5 NO
9. Which 5of 5the 5following 5molecules 5contain 5both 5covalent 5and 5ionic 5bonds?
A) I, 5II B) 5 I, 5IV C) 5 II, 5III D) 5II, 5IV
10. Arrange 5the 5following 5bonds 5in 5decreasing 5order 5of 5ionic 5character, 5putting 5the
5most5
ionic 5first.
A) I 5> 5II 5> 5III 5> 5IV C) IV 5> 5III 5> 5II 5> 5I
B) IV 5> 5II 5> 5I 5> 5III D) IV 5> 5II 5> 5III 5> 5I
11. Which 5of 5the 5following 5statements 5correctly 5describes 5the 5typical 5number 5of
5bonds 5for5
carbon, 5nitrogen, 5and 5oxygen 5in 5most 5neutral 5organic 5molecules?
A) Carbon 5forms 54 5covalent 5bonds, 5nitrogen 5forms 52 5covalent 5bonds 5and 5oxygen
5forms5 3 5covalent 5bonds.
B) Carbon 5forms 54 5covalent 5bonds, 5nitrogen 5forms 53 5covalent 5bonds 5and 5oxygen
5forms5 2 5covalent 5bonds.
Page 54
