TEST BANK for Organic Chemistry 6th Edition
x x x x x x
x Smith / All Chapters 1 - 29 / Full Complete
x x x x x x x x x
Page x1
,Chapter 1 Structure and Bonding
x x x x
Chapter 2 Acids and Bases
x x x x
Chapter 3 Introduction to Organic Molecules and Functional Groups
x x x x x x x x
Chapter 4 Alkanes
x x
Chapter 5 Stereochemistry
x x
Chapter 6 Understanding Organic Reactions
x x x x
Chapter 7 Alkyl Halides and Nucleophilic Substitution
x x x x x x
Chapter 8 Alkyl Halides and Elimination Reactions
x x x x x x
Chapter 9 Alcohols, Ethers, and Related Compounds
x x x x x x
Chapter 10 Alkenes and Addition Reactions
x x x x x
Chapter 11 Alkynes and Synthesis
x x x x
Chapter 12 Oxidation and Reduction
x x x x
Spectroscopy A Mass Spectrometry
x x x
Spectroscopy B Infrared Spectroscopy
x x x
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
x x x x x
Chapter 13 Radical Reactions
x x x
Chapter 14 Conjugation, Resonance, and Dienes
x x x x x
Chapter 15 Benzene and Aromatic Compounds
x x x x x
Chapter 16 Reactions of Aromatic Compounds
x x x x x
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
x x x x x x x
Oxidation and Reduction
x x x
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
x x x x x
Chapter 19 Carboxylic Acids and Nitriles
x x x x x
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
x x x x x x x x
Substitution
x
Chapter x 21 x Substitution Reactions of Carbonyl Compounds at the α-Carbon
x x x x x x x
Chapter x 22 x Carbonyl Condensation Reactions x x
Chapter x 23 x Amines
Chapter x 24 x Carbon-Carbon Bond-Forming Reactions in Organic Synthesis x x x x x
Chapter x 25 x Pericyclic Reactions x
Chapter x 26 x Carbohydrates
Chapter x 27 x Amino Acids and Proteins
x x x
Chapter x 28 x Synthetic Polymers x
Chapter x 29 x Lipids (Available online)
x x
Page x2
, Chapter 1: Structure and Bonding
x x x x
1. What xis xthe xground-state xelectronic xconfiguration xof xa xcarbon
2 2 5
xatom? xA) x 1s , x2s , x2p B) x 1s2, x2s2, x2p2 C) x 1s2, x2s2,
6 2 2 4
x2p D) x 1s , x2s , x2p
2. What xis xthe xground-state xelectronic xconfiguration xof xa xfluorine
A) x 1s2, x2s2, x2p2
xatom?x B) x 1s2, x2s2, x2p3 C) x 1s2, x2s2,
4
x2p D) x 1s2, x2s2, x2p5
3. What xis xthe xground-state xelectronic xconfiguration xof xa xmagnesium xcation
2+
x(Mg )?xA) 1s2, x2s2, x2p6 C) 1s2, x2s2,
6 2
x2p , x3s
B) 1s2, x2s2, x2p6, x3s1 D) 1s2, x2s2, x2p6, x3s2, x3p2
4. What xis xthe xground-state xelectronic xconfiguration xof xa xchlorine xanion
—
x(Cl )?xA) 1s2, x2s2, x2p6 C)
1s2, x2s2, x2p6, x3s2, x3p5
B) 1s2, x2s2, x2p6, x3s2, x3p6 D) 1s2, x2s2, x2p6, x3s2, x3p4
5. Which xof xthe xfollowing xstatements xabout xvalence xelectrons xis xtrue?
A) They xare xthe xmost xtightly xheld xelectrons.
B) They xdo xnot xparticipate xin xchemical xreactions.
Page x3
, Chapter x1: xStructure xand
xBonding
C) They xare xthe xoutermost xelectrons.
D) They xreveal xthe xperiod xnumber xof xa xsecond-row xelement.
6. Which xof xthe xfollowing xstatements xabout xbonding xis xtrue?
A) Covalent xbonds xresult xfrom xthe xtransfer xof xelectrons xfrom xone xelement xto xanother.
B) Ionic xbonds xresult xfrom xthe xtransfer xof xelectrons xfrom xa xmetal xto xa xnon-metal.
C) Ionic xbonds xresult xfrom xthe xsharing xof xelectrons xbetween xtwo xnon-metals.
D) Covalent xbonds xresult xfrom xthe xsharing xof xelectrons xbetween xtwo xmetals.
7. Which xof xthe xfollowing xwould xyou xexpect xto xhave xionic xbonds?
A) CO B) x FBr C) x NF3 D) x NaCl
8. Which xof xthe xfollowing xmolecules xhas xnonpolar xcovalent xbonds?
A) HCl B) x N2 C) x CHCl3 D) x NO
9. Which xof xthe xfollowing xmolecules xcontain xboth xcovalent xand xionic xbonds?
A) I, xII B) x I, xIV C) x II, xIII D) xII, xIV
10. Arrange xthe xfollowing xbonds xin xdecreasing xorder xof xionic xcharacter, xputting xthe
xmostx
ionic xfirst.
A) I x> xII x> xIII x> xIV C) IV x> xIII x> xII x> xI
B) IV x> xII x> xI x> xIII D) IV x> xII x> xIII x> xI
11. Which xof xthe xfollowing xstatements xcorrectly xdescribes xthe xtypical xnumber xof
xbonds xforx
carbon, xnitrogen, xand xoxygen xin xmost xneutral xorganic xmolecules?
A) Carbon xforms x4 xcovalent xbonds, xnitrogen xforms x2 xcovalent xbonds xand xoxygen
xformsx 3 xcovalent xbonds.
B) Carbon xforms x4 xcovalent xbonds, xnitrogen xforms x3 xcovalent xbonds xand xoxygen
xformsx 2 xcovalent xbonds.
Page x4
x x x x x x
x Smith / All Chapters 1 - 29 / Full Complete
x x x x x x x x x
Page x1
,Chapter 1 Structure and Bonding
x x x x
Chapter 2 Acids and Bases
x x x x
Chapter 3 Introduction to Organic Molecules and Functional Groups
x x x x x x x x
Chapter 4 Alkanes
x x
Chapter 5 Stereochemistry
x x
Chapter 6 Understanding Organic Reactions
x x x x
Chapter 7 Alkyl Halides and Nucleophilic Substitution
x x x x x x
Chapter 8 Alkyl Halides and Elimination Reactions
x x x x x x
Chapter 9 Alcohols, Ethers, and Related Compounds
x x x x x x
Chapter 10 Alkenes and Addition Reactions
x x x x x
Chapter 11 Alkynes and Synthesis
x x x x
Chapter 12 Oxidation and Reduction
x x x x
Spectroscopy A Mass Spectrometry
x x x
Spectroscopy B Infrared Spectroscopy
x x x
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
x x x x x
Chapter 13 Radical Reactions
x x x
Chapter 14 Conjugation, Resonance, and Dienes
x x x x x
Chapter 15 Benzene and Aromatic Compounds
x x x x x
Chapter 16 Reactions of Aromatic Compounds
x x x x x
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
x x x x x x x
Oxidation and Reduction
x x x
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
x x x x x
Chapter 19 Carboxylic Acids and Nitriles
x x x x x
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
x x x x x x x x
Substitution
x
Chapter x 21 x Substitution Reactions of Carbonyl Compounds at the α-Carbon
x x x x x x x
Chapter x 22 x Carbonyl Condensation Reactions x x
Chapter x 23 x Amines
Chapter x 24 x Carbon-Carbon Bond-Forming Reactions in Organic Synthesis x x x x x
Chapter x 25 x Pericyclic Reactions x
Chapter x 26 x Carbohydrates
Chapter x 27 x Amino Acids and Proteins
x x x
Chapter x 28 x Synthetic Polymers x
Chapter x 29 x Lipids (Available online)
x x
Page x2
, Chapter 1: Structure and Bonding
x x x x
1. What xis xthe xground-state xelectronic xconfiguration xof xa xcarbon
2 2 5
xatom? xA) x 1s , x2s , x2p B) x 1s2, x2s2, x2p2 C) x 1s2, x2s2,
6 2 2 4
x2p D) x 1s , x2s , x2p
2. What xis xthe xground-state xelectronic xconfiguration xof xa xfluorine
A) x 1s2, x2s2, x2p2
xatom?x B) x 1s2, x2s2, x2p3 C) x 1s2, x2s2,
4
x2p D) x 1s2, x2s2, x2p5
3. What xis xthe xground-state xelectronic xconfiguration xof xa xmagnesium xcation
2+
x(Mg )?xA) 1s2, x2s2, x2p6 C) 1s2, x2s2,
6 2
x2p , x3s
B) 1s2, x2s2, x2p6, x3s1 D) 1s2, x2s2, x2p6, x3s2, x3p2
4. What xis xthe xground-state xelectronic xconfiguration xof xa xchlorine xanion
—
x(Cl )?xA) 1s2, x2s2, x2p6 C)
1s2, x2s2, x2p6, x3s2, x3p5
B) 1s2, x2s2, x2p6, x3s2, x3p6 D) 1s2, x2s2, x2p6, x3s2, x3p4
5. Which xof xthe xfollowing xstatements xabout xvalence xelectrons xis xtrue?
A) They xare xthe xmost xtightly xheld xelectrons.
B) They xdo xnot xparticipate xin xchemical xreactions.
Page x3
, Chapter x1: xStructure xand
xBonding
C) They xare xthe xoutermost xelectrons.
D) They xreveal xthe xperiod xnumber xof xa xsecond-row xelement.
6. Which xof xthe xfollowing xstatements xabout xbonding xis xtrue?
A) Covalent xbonds xresult xfrom xthe xtransfer xof xelectrons xfrom xone xelement xto xanother.
B) Ionic xbonds xresult xfrom xthe xtransfer xof xelectrons xfrom xa xmetal xto xa xnon-metal.
C) Ionic xbonds xresult xfrom xthe xsharing xof xelectrons xbetween xtwo xnon-metals.
D) Covalent xbonds xresult xfrom xthe xsharing xof xelectrons xbetween xtwo xmetals.
7. Which xof xthe xfollowing xwould xyou xexpect xto xhave xionic xbonds?
A) CO B) x FBr C) x NF3 D) x NaCl
8. Which xof xthe xfollowing xmolecules xhas xnonpolar xcovalent xbonds?
A) HCl B) x N2 C) x CHCl3 D) x NO
9. Which xof xthe xfollowing xmolecules xcontain xboth xcovalent xand xionic xbonds?
A) I, xII B) x I, xIV C) x II, xIII D) xII, xIV
10. Arrange xthe xfollowing xbonds xin xdecreasing xorder xof xionic xcharacter, xputting xthe
xmostx
ionic xfirst.
A) I x> xII x> xIII x> xIV C) IV x> xIII x> xII x> xI
B) IV x> xII x> xI x> xIII D) IV x> xII x> xIII x> xI
11. Which xof xthe xfollowing xstatements xcorrectly xdescribes xthe xtypical xnumber xof
xbonds xforx
carbon, xnitrogen, xand xoxygen xin xmost xneutral xorganic xmolecules?
A) Carbon xforms x4 xcovalent xbonds, xnitrogen xforms x2 xcovalent xbonds xand xoxygen
xformsx 3 xcovalent xbonds.
B) Carbon xforms x4 xcovalent xbonds, xnitrogen xforms x3 xcovalent xbonds xand xoxygen
xformsx 2 xcovalent xbonds.
Page x4
