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Monday 10 June 2024 – Morning
A Level Chemistry A
H432/01 Periodic table, elements and physical chemistry
Time allowed: 2 hours 15 minutes
You must have:
the Data Sheet for Chemistry A
You can use:
a scientific or graphical calculator
an HB pencil
Please write clearly in black ink. Do not write in the barcodes.
Centre number Candidate number
First name(s)
INSTRUCTIONS
Last name
• Use black ink. You can use an HB pencil, but only for graphs and diagrams.
• Write your answer to each question in the space provided. If you need extra space use
the lined pages at the end of this booklet. The question numbers must be clearly shown.
• Answer all the questions.
• Where appropriate, your answer should be supported with working. Marks might be
given for using a correct method, even if your answer is wrong.
INFORMATION
• The total mark for this paper is 100.
• The marks for each question are shown in brackets [ ].
• Quality of extended response will be assessed in questions marked with an asterisk (*).
• This document has 32 pages.
ADVICE
• Read each question carefully before you start your answer.
Turn over
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, 2
SECTION A
You should spend a maximum of 20 minutes on this section.
Write your answer to each question in the box provided.
1 Oxygen has the electron configuration 1s22s22p4.
How are the electrons in an atom of oxygen arranged in the p-orbitals?
A
↑↑ ↑↑
B
↑↓ ↑↓
C
↑↑ ↑ ↑
D
↑↓ ↑ ↑
Your answer [1]
2 Water has the anomalous properties below.
• Water has relatively high melting and boiling points.
• Ice is less dense than water.
Which statement explains these anomalous properties?
A The covalent bonding within water molecules.
B The hydrogen bonding between water molecules.
C The induced dipole–dipole interactions (London forces) between water molecules.
D The ionic bonding between water molecules.
Your answer [1]
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, 3
3 Which chemical process is the most sustainable in terms of the atom economy of the iron
produced?
A Fe2O3 + 3CO 2Fe + 3CO2
B Fe2O3 + 3H2 2Fe + 3H2O
C 2Fe2O3 4Fe + 3O2
D 2Fe2O3 + 3C 4Fe + 3CO2
Your answer [1]
4 Which compounds of magnesium can be used as ‘antacids’?
A Chlorides
B Hydroxides
C Nitrates
D Sulfates
Your answer [1]
5 Which statement explains the trend in boiling points down the halogens group?
A The bond enthalpy of the covalent bonds increases.
B The halogens become less electronegative.
C The induced dipole–dipole interactions (London forces) become stronger.
D The reactivity of the halogens decreases.
Your answer [1]
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, 4
6 Which equation does not represent a disproportionation reaction?
A Cl2 + H2O HClO + HCl
B Cl2 + 2NaOH NaClO + NaCl + H2O
C 4KClO3 KCl + 3KClO4
D 4HCl + MnO2 MnCl2 + Cl2 + 2H2O
Your answer [1]
7 The equation for the reaction of sulfuric acid with potassium hydroxide is shown
below. H2SO4(aq) + 2KOH(aq) K2SO4(aq) + 2H2O(l)
25 cm3 of 1.00 mol dm–3 H2SO4 is reacted with excess
KOH. The energy given out is 2.8 kJ.
What is the enthalpy change of neutralisation, in kJ mol–1?
A –56
B –70
C –112
D –224
Your answer [1]
8 Which row in the table explains how a catalyst affects the activation energy (Ea) and the
proportion of molecules with energy > Ea?
How the activation Proportion of molecules
energy changes with energy > Ea
A decreases decreases
B decreases increases
C increases decreases
D increases increases
Your answer [1]
verified
Monday 10 June 2024 – Morning
A Level Chemistry A
H432/01 Periodic table, elements and physical chemistry
Time allowed: 2 hours 15 minutes
You must have:
the Data Sheet for Chemistry A
You can use:
a scientific or graphical calculator
an HB pencil
Please write clearly in black ink. Do not write in the barcodes.
Centre number Candidate number
First name(s)
INSTRUCTIONS
Last name
• Use black ink. You can use an HB pencil, but only for graphs and diagrams.
• Write your answer to each question in the space provided. If you need extra space use
the lined pages at the end of this booklet. The question numbers must be clearly shown.
• Answer all the questions.
• Where appropriate, your answer should be supported with working. Marks might be
given for using a correct method, even if your answer is wrong.
INFORMATION
• The total mark for this paper is 100.
• The marks for each question are shown in brackets [ ].
• Quality of extended response will be assessed in questions marked with an asterisk (*).
• This document has 32 pages.
ADVICE
• Read each question carefully before you start your answer.
Turn over
verified
, 2
SECTION A
You should spend a maximum of 20 minutes on this section.
Write your answer to each question in the box provided.
1 Oxygen has the electron configuration 1s22s22p4.
How are the electrons in an atom of oxygen arranged in the p-orbitals?
A
↑↑ ↑↑
B
↑↓ ↑↓
C
↑↑ ↑ ↑
D
↑↓ ↑ ↑
Your answer [1]
2 Water has the anomalous properties below.
• Water has relatively high melting and boiling points.
• Ice is less dense than water.
Which statement explains these anomalous properties?
A The covalent bonding within water molecules.
B The hydrogen bonding between water molecules.
C The induced dipole–dipole interactions (London forces) between water molecules.
D The ionic bonding between water molecules.
Your answer [1]
verified
, 3
3 Which chemical process is the most sustainable in terms of the atom economy of the iron
produced?
A Fe2O3 + 3CO 2Fe + 3CO2
B Fe2O3 + 3H2 2Fe + 3H2O
C 2Fe2O3 4Fe + 3O2
D 2Fe2O3 + 3C 4Fe + 3CO2
Your answer [1]
4 Which compounds of magnesium can be used as ‘antacids’?
A Chlorides
B Hydroxides
C Nitrates
D Sulfates
Your answer [1]
5 Which statement explains the trend in boiling points down the halogens group?
A The bond enthalpy of the covalent bonds increases.
B The halogens become less electronegative.
C The induced dipole–dipole interactions (London forces) become stronger.
D The reactivity of the halogens decreases.
Your answer [1]
verified Turn over
, 4
6 Which equation does not represent a disproportionation reaction?
A Cl2 + H2O HClO + HCl
B Cl2 + 2NaOH NaClO + NaCl + H2O
C 4KClO3 KCl + 3KClO4
D 4HCl + MnO2 MnCl2 + Cl2 + 2H2O
Your answer [1]
7 The equation for the reaction of sulfuric acid with potassium hydroxide is shown
below. H2SO4(aq) + 2KOH(aq) K2SO4(aq) + 2H2O(l)
25 cm3 of 1.00 mol dm–3 H2SO4 is reacted with excess
KOH. The energy given out is 2.8 kJ.
What is the enthalpy change of neutralisation, in kJ mol–1?
A –56
B –70
C –112
D –224
Your answer [1]
8 Which row in the table explains how a catalyst affects the activation energy (Ea) and the
proportion of molecules with energy > Ea?
How the activation Proportion of molecules
energy changes with energy > Ea
A decreases decreases
B decreases increases
C increases decreases
D increases increases
Your answer [1]
verified
