0 of\ische chem,e ru nol-if\es
l-es L' N,tc\eo ['ele qciC rFres OP sqirL)ort) I
o o
il il
c c
/'\
R R RLI
heForr o tdeh.y cje. teeide z3n cc:rbon\l
Nac
o
rt
,c, o
n o
H H t t,'.
fbrmatciehlde,
cu.cx, c\r/ $
C-p
brr t gi6q;l o
ll
benz<.ldeh1ele
o
ll 't{SC
,t-*
0 o
C ll !l
-clt: c ogsvcrldehlde
Hsc cHa " : ethorrCil
Qcel.on 'verder or\deren
OCe.Fcr -l crcevic <:cid
[e,^t6n benzo ferron
I tre.t c rrot4)
E, (1*e,
Polcirre r^no\ecu\€ dcor 50ti
dipornror.nenF
tt we"schr:.rv,,1g von g -e- ..+A
Aldertvoe Srorere 5*
doo xe,Fq:,6 R/ 3-\ n
t$?nk R
S.*tr vcn xehon : indoc,F.reve
- - I Sever
$ee [r e ir\e€r nqgcri ef )
GEvouG ' Nuc\eofie\
setsde,n dectr)e varv q)Ercr op clce,h.lde
=) O ldehyden zJtn rr\eer !-eect-ief dOrt tret-onen
o9
\r o
I\ur, d 5'
/\
RH
Nu clec: [ne\e cicln VL; i OP LU,*'1O
u -or o i1
TT
3=.8'
R 0 u- LJ
Lumo = L,crr.r Un o.".rp\e,c, Mole,cu\c,r Orbilsi t niekgevuld rrroieculoir orbilqori
@
, Nuc\eo[ie.\e,n :
o
HOr h.ydroxide ion
Hou hldrcrOi-
Hro hrydr'rde ion RQH her.n\ Ocel-CrCl i c,ce,Yrul
R3c? Crllaoxide \on HsN "iff\rf\e
N =c
I Cr;on\de ioQ Rxrpt 2 lprf\e
Tt.l ,a N oxjne, / n.{drsxtl qri'n-e
ll2 -o!\
Nl'12-NUz lrldro zon I irgdrozne
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llecrct ,e_r
------
A lden*yde en kehcn nucreofiete, cddiFie, AN
UarbofiZuur de.', vcf Fen
AN
lOt ,fHo ol{
o}I* R AR ,,A R
o\ N'ir R
l$u: lrlur
i6rP o
l/
S" nE
R
oT
L R\r"'jY A L
@
lr\u *\
R t\,o
Ntl :
Cyon\de \Oten C0firlu\\en op nuc\eo[iet '
R/ttr{
ll NoCN
HrO, Hcr
*x" rt
R lt
o CN
l t
efl H
N
k"" }"
R H
@
,l\n o HO t40 r{
ll
t t,., \,,H H-O' o
r{cN c >
C /a
c L0orffrte \
6rt
-) v-
@ -L:N
;4+
cooH
Aonvol von No B Hu ncr Y r r u \.nboe>r\r 1 dr idg
oT tOrO
DLI*o tl
o il I
Hsc
C a)
--t rl r ,/7
rbq- I \ ' l{
li
@
Oce,kc.tdets\yde
H
l{
rLo'*
+ HrC - C -Or"l
I
Her oHen\de t,locsi} tr;*ffi:I*
OGn'ZiJr€.n I
l{ '+ BH*- lbao'tr1dr,de.) Feductof
)
ffi V
G, l-i AlUu 'ls een sverker reduchon"'>
b \ir*ri.r,t olur.rr\nir.fl hYdtide
t"''sg
HAAR 5e.rcio.$K '4 Y\iet
1^1€1tt€\
Y
& hlldride reduceerh
er'\Kel
: kehOnen en qldehyden (er'
'.'u"hroridenl
D-sRu :
esl-e.r5 redr.rcere6 ngq1- Oiderrycle.fi
l" t{
I
-\ AI '.'\
dii sg Sarru I cllr.ryninru,-nhqd r rde
($l o
H
o -+ \ PT
t{ c c\
bc '6-. H2-CH3 l'bc l.l
o-
ro -R
e,Lhllaeercq,l.
16ro
I
- Asc / c
I
H
H
o
Volf - Kish.,,.. Reductje @ R ,\ R
@ @
C \ern,-n.",r3l Redr.rvie H2NN l{r Znr\\ ri4crrA
e) +
+ ccrrbonq\ reduceren tol- (
K0$
2o'srop )
Gllaglcr6 lzic p6l
R R'
@
, o (-inC) - i-ne.tsocrl c-,cJCiYre
LithiurO : Ster|4 recjercFans =.Sr"[" s{ ->
g.o- e'- sch5ljven cls Li @
......._>
i6rg
f,- ,'f.. H
c I't
3
hc,o Ll o
cQrbonion
G rgncrd rectchte
R-x _Is> RTs X
rormrtg ccirbonrcro
G.gnci"C recigP_os tr/s@ ,IP
is!=..g, orag t^te.rken uant
g eonvc;ck vnev H1t3
RH a Seen reoerig
eo
@
R
Er - \Br to o TgB.
or.l
R' H.O
If Rr R l'{ '
El-
EI,
Grgncnd rel
qdd iFie een nuc\eofiele, r0ternrsch rne19.tel
f-..H:s ]oerL N0nF chirqgrl C€plr,,yy1
k";^;;,'
$€cundqir
;:."jilt9H'"J*::;" I hogt o{ von grrnhte
qlcohol" nd
st."P"n
C)
t\ eccLje vgn C-llcoFrol e,n otctehyde,
o H+ '"0- l'l z14
/s; 'l "/\
n(DJ o El-l3|t
^ R u
R l+
C drclr rgclcr&n ->
C vorl.d5 ? ge,lcdc,n
'--) uox- .-H+
.-_? HO OEF
R do-u
/IV
El,0ll EFO 0 El-
El- Rt{ 'tot
hemic.,ce,'rqcil -)
Occtcql
\$0rdt
Fl-0U . eLhqnol Sevorrnd b5
tcc.ves\1g vordoendc
Uc-clrz-or{ QlcoYrot
@
l-es L' N,tc\eo ['ele qciC rFres OP sqirL)ort) I
o o
il il
c c
/'\
R R RLI
heForr o tdeh.y cje. teeide z3n cc:rbon\l
Nac
o
rt
,c, o
n o
H H t t,'.
fbrmatciehlde,
cu.cx, c\r/ $
C-p
brr t gi6q;l o
ll
benz<.ldeh1ele
o
ll 't{SC
,t-*
0 o
C ll !l
-clt: c ogsvcrldehlde
Hsc cHa " : ethorrCil
Qcel.on 'verder or\deren
OCe.Fcr -l crcevic <:cid
[e,^t6n benzo ferron
I tre.t c rrot4)
E, (1*e,
Polcirre r^no\ecu\€ dcor 50ti
dipornror.nenF
tt we"schr:.rv,,1g von g -e- ..+A
Aldertvoe Srorere 5*
doo xe,Fq:,6 R/ 3-\ n
t$?nk R
S.*tr vcn xehon : indoc,F.reve
- - I Sever
$ee [r e ir\e€r nqgcri ef )
GEvouG ' Nuc\eofie\
setsde,n dectr)e varv q)Ercr op clce,h.lde
=) O ldehyden zJtn rr\eer !-eect-ief dOrt tret-onen
o9
\r o
I\ur, d 5'
/\
RH
Nu clec: [ne\e cicln VL; i OP LU,*'1O
u -or o i1
TT
3=.8'
R 0 u- LJ
Lumo = L,crr.r Un o.".rp\e,c, Mole,cu\c,r Orbilsi t niekgevuld rrroieculoir orbilqori
@
, Nuc\eo[ie.\e,n :
o
HOr h.ydroxide ion
Hou hldrcrOi-
Hro hrydr'rde ion RQH her.n\ Ocel-CrCl i c,ce,Yrul
R3c? Crllaoxide \on HsN "iff\rf\e
N =c
I Cr;on\de ioQ Rxrpt 2 lprf\e
Tt.l ,a N oxjne, / n.{drsxtl qri'n-e
ll2 -o!\
Nl'12-NUz lrldro zon I irgdrozne
\$U: ineuruui)
llecrct ,e_r
------
A lden*yde en kehcn nucreofiete, cddiFie, AN
UarbofiZuur de.', vcf Fen
AN
lOt ,fHo ol{
o}I* R AR ,,A R
o\ N'ir R
l$u: lrlur
i6rP o
l/
S" nE
R
oT
L R\r"'jY A L
@
lr\u *\
R t\,o
Ntl :
Cyon\de \Oten C0firlu\\en op nuc\eo[iet '
R/ttr{
ll NoCN
HrO, Hcr
*x" rt
R lt
o CN
l t
efl H
N
k"" }"
R H
@
,l\n o HO t40 r{
ll
t t,., \,,H H-O' o
r{cN c >
C /a
c L0orffrte \
6rt
-) v-
@ -L:N
;4+
cooH
Aonvol von No B Hu ncr Y r r u \.nboe>r\r 1 dr idg
oT tOrO
DLI*o tl
o il I
Hsc
C a)
--t rl r ,/7
rbq- I \ ' l{
li
@
Oce,kc.tdets\yde
H
l{
rLo'*
+ HrC - C -Or"l
I
Her oHen\de t,locsi} tr;*ffi:I*
OGn'ZiJr€.n I
l{ '+ BH*- lbao'tr1dr,de.) Feductof
)
ffi V
G, l-i AlUu 'ls een sverker reduchon"'>
b \ir*ri.r,t olur.rr\nir.fl hYdtide
t"''sg
HAAR 5e.rcio.$K '4 Y\iet
1^1€1tt€\
Y
& hlldride reduceerh
er'\Kel
: kehOnen en qldehyden (er'
'.'u"hroridenl
D-sRu :
esl-e.r5 redr.rcere6 ngq1- Oiderrycle.fi
l" t{
I
-\ AI '.'\
dii sg Sarru I cllr.ryninru,-nhqd r rde
($l o
H
o -+ \ PT
t{ c c\
bc '6-. H2-CH3 l'bc l.l
o-
ro -R
e,Lhllaeercq,l.
16ro
I
- Asc / c
I
H
H
o
Volf - Kish.,,.. Reductje @ R ,\ R
@ @
C \ern,-n.",r3l Redr.rvie H2NN l{r Znr\\ ri4crrA
e) +
+ ccrrbonq\ reduceren tol- (
K0$
2o'srop )
Gllaglcr6 lzic p6l
R R'
@
, o (-inC) - i-ne.tsocrl c-,cJCiYre
LithiurO : Ster|4 recjercFans =.Sr"[" s{ ->
g.o- e'- sch5ljven cls Li @
......._>
i6rg
f,- ,'f.. H
c I't
3
hc,o Ll o
cQrbonion
G rgncrd rectchte
R-x _Is> RTs X
rormrtg ccirbonrcro
G.gnci"C recigP_os tr/s@ ,IP
is!=..g, orag t^te.rken uant
g eonvc;ck vnev H1t3
RH a Seen reoerig
eo
@
R
Er - \Br to o TgB.
or.l
R' H.O
If Rr R l'{ '
El-
EI,
Grgncnd rel
qdd iFie een nuc\eofiele, r0ternrsch rne19.tel
f-..H:s ]oerL N0nF chirqgrl C€plr,,yy1
k";^;;,'
$€cundqir
;:."jilt9H'"J*::;" I hogt o{ von grrnhte
qlcohol" nd
st."P"n
C)
t\ eccLje vgn C-llcoFrol e,n otctehyde,
o H+ '"0- l'l z14
/s; 'l "/\
n(DJ o El-l3|t
^ R u
R l+
C drclr rgclcr&n ->
C vorl.d5 ? ge,lcdc,n
'--) uox- .-H+
.-_? HO OEF
R do-u
/IV
El,0ll EFO 0 El-
El- Rt{ 'tot
hemic.,ce,'rqcil -)
Occtcql
\$0rdt
Fl-0U . eLhqnol Sevorrnd b5
tcc.ves\1g vordoendc
Uc-clrz-or{ QlcoYrot
@
