TEST BANK for Organic Chemistry 6th Edition
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fg Smith / All Chapters 1 - 29 / Full Complete
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Page 1
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,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter fg 21 fg Substitution Reactions of Carbonyl Compounds at the α-Carbon fg fg fg fg fg fg fg
Chapter fg 22 fg Carbonyl Condensation Reactions fg fg
Chapter fg 23 fg Amines
Chapter fg 24 fg Carbon-Carbon Bond-Forming Reactions in Organic Synthesis fg fg fg fg fg
Chapter fg 25 fg Pericyclic Reactions fg
Chapter fg 26 fg Carbohydrates
Chapter fg 27 fg Amino Acids and Proteins
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Chapter fg 28 fg Synthetic Polymers fg
Chapter fg 29 fg Lipids (Available online)
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Page 2 fg
, Chapter 1: Structure and Bonding fg fg fg fg
1. What is the ground-state electronic configuration of a carbon
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atom? A) 1s2, 2s2, 2p5
fg fg B) 1s2, 2s2, 2p2 C) 1s2, 2s2,
f g fg fg f g fg fg f g fg
6 2 2 4
2p
fg D) 1s , 2s , 2p f g fg fg
2. What is the ground-state electronic configuration of a fluorine
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atom?A) 1s2, 2s2, 2p2
fg gf f gB) 1s2, 2s2, 2p3 C) 1s2, 2s2,
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2p4
fg D) 1s2, 2s2, 2p5 f g fg fg
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)?A)
fg gf 1s2, 2s2, 2p6C) 1s2, 2s2, 2p6, fg fg fg fg
3s2
fg
B) 1s2, 2s2, 2p6, 3s1 fg fg fg D) 1s2, 2s2, 2p6, 3s2, 3p2 fg fg fg fg
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
gf fg C) 1s2, 2s2, 2p6, 3s2, 3p5
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B) 1s2, 2s2, 2p6, 3s2, 3p6 fg fg fg fg D) 1s2, 2s2, 2p6, 3s2, 3p4 fg fg fg fg
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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, Chapter 1: Structure and fg fg fg
Bonding
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C) They are the outermost electrons.
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D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl f g f g f g
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO f g f g f g
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B)fg f g I, IV C)
fg f g II, III D) II, IV
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10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
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A) I > II > III > IV
fg fg fg fg fg fg C) IV > III > II > I fg fg fg fg fg fg
B) IV > II > I > III fg fg fg fg fg fg D) IV > II > III > I fg fg fg fg fg fg
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms2 covalent bonds.
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Page 4 fg
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fg Smith / All Chapters 1 - 29 / Full Complete
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Page 1
fg
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter fg 21 fg Substitution Reactions of Carbonyl Compounds at the α-Carbon fg fg fg fg fg fg fg
Chapter fg 22 fg Carbonyl Condensation Reactions fg fg
Chapter fg 23 fg Amines
Chapter fg 24 fg Carbon-Carbon Bond-Forming Reactions in Organic Synthesis fg fg fg fg fg
Chapter fg 25 fg Pericyclic Reactions fg
Chapter fg 26 fg Carbohydrates
Chapter fg 27 fg Amino Acids and Proteins
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Chapter fg 28 fg Synthetic Polymers fg
Chapter fg 29 fg Lipids (Available online)
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Page 2 fg
, Chapter 1: Structure and Bonding fg fg fg fg
1. What is the ground-state electronic configuration of a carbon
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atom? A) 1s2, 2s2, 2p5
fg fg B) 1s2, 2s2, 2p2 C) 1s2, 2s2,
f g fg fg f g fg fg f g fg
6 2 2 4
2p
fg D) 1s , 2s , 2p f g fg fg
2. What is the ground-state electronic configuration of a fluorine
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atom?A) 1s2, 2s2, 2p2
fg gf f gB) 1s2, 2s2, 2p3 C) 1s2, 2s2,
fg fg f g fg fg f g fg
2p4
fg D) 1s2, 2s2, 2p5 f g fg fg
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)?A)
fg gf 1s2, 2s2, 2p6C) 1s2, 2s2, 2p6, fg fg fg fg
3s2
fg
B) 1s2, 2s2, 2p6, 3s1 fg fg fg D) 1s2, 2s2, 2p6, 3s2, 3p2 fg fg fg fg
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
gf fg C) 1s2, 2s2, 2p6, 3s2, 3p5
fg fg fg fg fg
B) 1s2, 2s2, 2p6, 3s2, 3p6 fg fg fg fg D) 1s2, 2s2, 2p6, 3s2, 3p4 fg fg fg fg
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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Page 3 fg
, Chapter 1: Structure and fg fg fg
Bonding
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C) They are the outermost electrons.
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D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
fg fg fg fg fg fg fg fg fg fg fg fg
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl f g f g f g
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO f g f g f g
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B)fg f g I, IV C)
fg f g II, III D) II, IV
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10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
fg gf fg
A) I > II > III > IV
fg fg fg fg fg fg C) IV > III > II > I fg fg fg fg fg fg
B) IV > II > I > III fg fg fg fg fg fg D) IV > II > III > I fg fg fg fg fg fg
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms2 covalent bonds.
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