TEST BANK for Organic Chemistry 6th Edition Smith
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/ All Chapters 1 - 29 / Full Complete
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Page |1
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22 Carbonyl Condensation Reactions
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Chapter 23 Amines
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Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25 Pericyclic Reactions
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Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
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Chapter 28 Synthetic Polymers
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Chapter 29 Lipids (Available online)
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Page |2
, Chapter 1: Structure and Bonding
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1. What |is |the |ground-state |electronic |configuration |of |a |carbon |atom?
2 2 5
|A) | 1s , |2s , |2p B) | 1s2, |2s2, |2p2 C) | 1s2, |2s2, |2p6 D) | 1s2, |2s2, |2p4
2. What |is |the |ground-state |electronic |configuration |of |a |fluorine |atom?
2 2 2
|A) | 1s , |2s , |2p B) | 1s2, |2s2, |2p3 C) | 1s2, |2s2, |2p4 D) | 1s2, |2s2, |2p5
3. What |is |the |ground-state |electronic |configuration |of |a |magnesium |cation |(Mg2+)?
|A) 1s2, |2s2, |2p6 C) 1s2, |2s2, |2p6, |3s2
B) 1s2, |2s2, |2p6, |3s1 D) 1s2, |2s2, |2p6, |3s2, |3p2
4. What |is |the |ground-state |electronic |configuration |of |a |chlorine |anion |(Cl—)?
|A) 1s2, |2s2, |2p6 C) 1s2, |2s2, |2p6, |3s2, |3p5
B) 1s2, |2s2, |2p6, |3s2, |3p6 D) 1s2, |2s2, |2p6, |3s2, |3p4
5. Which |of |the |following |statements |about |valence |electrons |is |true?
A) They |are |the |most |tightly |held |electrons.
B) They |do |not |participate |in |chemical |reactions.
Page |3
, Chapter |1: |Structure |and |Bonding
C) They |are |the |outermost |electrons.
D) They |reveal |the |period |number |of |a |second-row |element.
6. Which |of |the |following |statements |about |bonding |is |true?
A) Covalent |bonds |result |from |the |transfer |of |electrons |from |one |element |to |another.
B) Ionic |bonds |result |from |the |transfer |of |electrons |from |a |metal |to |a |non-metal.
C) Ionic |bonds |result |from |the |sharing |of |electrons |between |two |non-metals.
D) Covalent |bonds |result |from |the |sharing |of |electrons |between |two |metals.
7. Which |of |the |following |would |you |expect |to |have |ionic |bonds?
A) CO B) | FBr C) | NF3 D) | NaCl
8. Which |of |the |following |molecules |has |nonpolar |covalent |bonds?
A) HCl B) | N2 C) | CHCl3 D) | NO
9. Which |of |the |following |molecules |contain |both |covalent |and |ionic |bonds?
A) I, |II B) | I, |IV C) | II, |III D) |II, |IV
10. Arrange |the |following |bonds |in |decreasing |order |of |ionic |character, |putting |the |most
|ionic |first.
A) I |> |II |> |III |> |IV C) IV |> |III |> |II |> |I
B) IV |> |II |> |I |> |III D) IV |> |II |> |III |> |I
11. Which |of |the |following |statements |correctly |describes |the |typical |number |of |bonds |for
|carbon, |nitrogen, |and |oxygen |in |most |neutral |organic |molecules?
A) Carbon |forms |4 |covalent |bonds, |nitrogen |forms |2 |covalent |bonds |and |oxygen |forms|3
|covalent |bonds.
B) Carbon |forms |4 |covalent |bonds, |nitrogen |forms |3 |covalent |bonds |and |oxygen |forms|2
|covalent |bonds.
Page |4
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/ All Chapters 1 - 29 / Full Complete
| | | | | | | | |
Page |1
,Chapter 1 Structure and Bonding
| | | |
Chapter 2 Acids and Bases
| | | |
Chapter 3 Introduction to Organic Molecules and Functional Groups
| | | | | | | |
Chapter 4 Alkanes
| |
Chapter 5 Stereochemistry
| |
Chapter 6 Understanding Organic Reactions
| | | |
Chapter 7 Alkyl Halides and Nucleophilic Substitution
| | | | | |
Chapter 8 Alkyl Halides and Elimination Reactions
| | | | | |
Chapter 9 Alcohols, Ethers, and Related Compounds
| | | | | |
Chapter 10 Alkenes and Addition Reactions
| | | | |
Chapter 11 Alkynes and Synthesis
| | | |
Chapter 12 Oxidation and Reduction
| | | |
Spectroscopy A Mass Spectrometry
| | |
Spectroscopy B Infrared Spectroscopy
| | |
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
| | | | |
Chapter 13 Radical Reactions
| | |
Chapter 14 Conjugation, Resonance, and Dienes
| | | | |
Chapter 15 Benzene and Aromatic Compounds
| | | | |
Chapter 16 Reactions of Aromatic Compounds
| | | | |
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
| | | | | | |
Oxidation and Reduction
| | |
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
| | | | |
Chapter 19 Carboxylic Acids and Nitriles
| | | | |
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
| | | | | | | |
Substitution
|
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
| | | | | | | | |
Chapter 22 Carbonyl Condensation Reactions
| | | |
Chapter 23 Amines
| |
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
| | | | | | |
Chapter 25 Pericyclic Reactions
| | |
Chapter 26 Carbohydrates
| |
Chapter 27 Amino Acids and Proteins
| | | | |
Chapter 28 Synthetic Polymers
| | |
Chapter 29 Lipids (Available online)
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Page |2
, Chapter 1: Structure and Bonding
| | | |
1. What |is |the |ground-state |electronic |configuration |of |a |carbon |atom?
2 2 5
|A) | 1s , |2s , |2p B) | 1s2, |2s2, |2p2 C) | 1s2, |2s2, |2p6 D) | 1s2, |2s2, |2p4
2. What |is |the |ground-state |electronic |configuration |of |a |fluorine |atom?
2 2 2
|A) | 1s , |2s , |2p B) | 1s2, |2s2, |2p3 C) | 1s2, |2s2, |2p4 D) | 1s2, |2s2, |2p5
3. What |is |the |ground-state |electronic |configuration |of |a |magnesium |cation |(Mg2+)?
|A) 1s2, |2s2, |2p6 C) 1s2, |2s2, |2p6, |3s2
B) 1s2, |2s2, |2p6, |3s1 D) 1s2, |2s2, |2p6, |3s2, |3p2
4. What |is |the |ground-state |electronic |configuration |of |a |chlorine |anion |(Cl—)?
|A) 1s2, |2s2, |2p6 C) 1s2, |2s2, |2p6, |3s2, |3p5
B) 1s2, |2s2, |2p6, |3s2, |3p6 D) 1s2, |2s2, |2p6, |3s2, |3p4
5. Which |of |the |following |statements |about |valence |electrons |is |true?
A) They |are |the |most |tightly |held |electrons.
B) They |do |not |participate |in |chemical |reactions.
Page |3
, Chapter |1: |Structure |and |Bonding
C) They |are |the |outermost |electrons.
D) They |reveal |the |period |number |of |a |second-row |element.
6. Which |of |the |following |statements |about |bonding |is |true?
A) Covalent |bonds |result |from |the |transfer |of |electrons |from |one |element |to |another.
B) Ionic |bonds |result |from |the |transfer |of |electrons |from |a |metal |to |a |non-metal.
C) Ionic |bonds |result |from |the |sharing |of |electrons |between |two |non-metals.
D) Covalent |bonds |result |from |the |sharing |of |electrons |between |two |metals.
7. Which |of |the |following |would |you |expect |to |have |ionic |bonds?
A) CO B) | FBr C) | NF3 D) | NaCl
8. Which |of |the |following |molecules |has |nonpolar |covalent |bonds?
A) HCl B) | N2 C) | CHCl3 D) | NO
9. Which |of |the |following |molecules |contain |both |covalent |and |ionic |bonds?
A) I, |II B) | I, |IV C) | II, |III D) |II, |IV
10. Arrange |the |following |bonds |in |decreasing |order |of |ionic |character, |putting |the |most
|ionic |first.
A) I |> |II |> |III |> |IV C) IV |> |III |> |II |> |I
B) IV |> |II |> |I |> |III D) IV |> |II |> |III |> |I
11. Which |of |the |following |statements |correctly |describes |the |typical |number |of |bonds |for
|carbon, |nitrogen, |and |oxygen |in |most |neutral |organic |molecules?
A) Carbon |forms |4 |covalent |bonds, |nitrogen |forms |2 |covalent |bonds |and |oxygen |forms|3
|covalent |bonds.
B) Carbon |forms |4 |covalent |bonds, |nitrogen |forms |3 |covalent |bonds |and |oxygen |forms|2
|covalent |bonds.
Page |4
