TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
Chapter 2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups
Chapter 4 Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions
Chapter 9 Alcohols, Ethers, and Related Compounds
Chapter 10 Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis
Chapter 12 Oxidation and Reduction
Spectroscopy A Mass Spectrometry
Spectroscopy B Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
Chapter 13 Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes
Chapter 15 Benzene and Aromatic Compounds
Chapter 16 Reactions of Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
Chapter 19 Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
Chapter 25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers
Chapter 29 Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding
C) They sare sthe soutermost selectrons.
D) They sreveal sthe speriod snumber sof sa ssecond-row selement.
6. Which sof sthe sfollowing sstatements sabout sbonding sis strue?
A) Covalent sbonds sresult sfrom sthe stransfer sof selectrons sfrom sone selement sto sanother.
B) Ionic sbonds sresult sfrom sthe stransfer sof selectrons sfrom sa smetal sto sa snon-metal.
C) Ionic sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo snon-metals.
D) Covalent sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo smetals.
7. Which sof sthe sfollowing swould syou sexpect sto shave sionic sbonds?
A) CO B) s FBr C) s NF3 D) s NaCl
8. Which sof sthe sfollowing smolecules shas snonpolar scovalent sbonds?
A) HCl B) s N2 C) s CHCl3 D) s NO
9. Which sof sthe sfollowing smolecules scontain sboth scovalent sand sionic sbonds?
A) I, sII B) s I, sIV C) s II, sIII D) sII, sIV
10. Arrange sthe sfollowing sbonds sin sdecreasing sorder sof sionic scharacter, sputting sthe
smostsionic sfirst.
A) I s> sII s> sIII s> sIV C) IV s> sIII s> sII s> sI
B) IV s> sII s> sI s> sIII D) IV s> sII s> sIII s> sI
11. Which sof sthe sfollowing sstatements scorrectly sdescribes sthe stypical snumber sof
sbonds sforscarbon, snitrogen, sand soxygen sin smost sneutral sorganic smolecules?
A) Carbon sforms s4 scovalent sbonds, snitrogen sforms s2 scovalent sbonds sand soxygen
sformss3 scovalent sbonds.
B) Carbon sforms s4 scovalent sbonds, snitrogen sforms s3 scovalent sbonds sand soxygen
sformss2 scovalent sbonds.
Page 4
Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
Chapter 2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups
Chapter 4 Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions
Chapter 9 Alcohols, Ethers, and Related Compounds
Chapter 10 Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis
Chapter 12 Oxidation and Reduction
Spectroscopy A Mass Spectrometry
Spectroscopy B Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
Chapter 13 Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes
Chapter 15 Benzene and Aromatic Compounds
Chapter 16 Reactions of Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
Chapter 19 Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
Chapter 25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers
Chapter 29 Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
Page 3
, Chapter 1: Structure and Bonding
C) They sare sthe soutermost selectrons.
D) They sreveal sthe speriod snumber sof sa ssecond-row selement.
6. Which sof sthe sfollowing sstatements sabout sbonding sis strue?
A) Covalent sbonds sresult sfrom sthe stransfer sof selectrons sfrom sone selement sto sanother.
B) Ionic sbonds sresult sfrom sthe stransfer sof selectrons sfrom sa smetal sto sa snon-metal.
C) Ionic sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo snon-metals.
D) Covalent sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo smetals.
7. Which sof sthe sfollowing swould syou sexpect sto shave sionic sbonds?
A) CO B) s FBr C) s NF3 D) s NaCl
8. Which sof sthe sfollowing smolecules shas snonpolar scovalent sbonds?
A) HCl B) s N2 C) s CHCl3 D) s NO
9. Which sof sthe sfollowing smolecules scontain sboth scovalent sand sionic sbonds?
A) I, sII B) s I, sIV C) s II, sIII D) sII, sIV
10. Arrange sthe sfollowing sbonds sin sdecreasing sorder sof sionic scharacter, sputting sthe
smostsionic sfirst.
A) I s> sII s> sIII s> sIV C) IV s> sIII s> sII s> sI
B) IV s> sII s> sI s> sIII D) IV s> sII s> sIII s> sI
11. Which sof sthe sfollowing sstatements scorrectly sdescribes sthe stypical snumber sof
sbonds sforscarbon, snitrogen, sand soxygen sin smost sneutral sorganic smolecules?
A) Carbon sforms s4 scovalent sbonds, snitrogen sforms s2 scovalent sbonds sand soxygen
sformss3 scovalent sbonds.
B) Carbon sforms s4 scovalent sbonds, snitrogen sforms s3 scovalent sbonds sand soxygen
sformss2 scovalent sbonds.
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