TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Pagelv1
,Chapterlv1lvStructurelvandlvBonding
Chapterlv2lvAcidslvandlvBases
Chapterlv3lvIntroductionlvtolvOrganiclvMoleculeslvandlvFunctionallvGroups
Chapterlv4lvAlkanes
Chapterlv5lvStereochemistry
Chapterlv6lvUnderstandinglvOrganiclvReactions
Chapterlv7lvAlkyllvHalideslvandlvNucleophiliclvSubstitution
Chapterlv8lvAlkyllvHalideslvandlvEliminationlvReactions
Chapterlv9lvAlcohols,lvEthers,lvandlvRelatedlvCompounds
Chapterlv10lvAlkeneslvandlvAdditionlvReactions
Chapterlv11lvAlkyneslvandlvSynthesis
Chapterlv12lvOxidationlvandlvReduction
SpectroscopylvAlvMasslvSpectrometry
SpectroscopylvBlvInfraredlvSpectroscopy
SpectroscopylvClvNuclearlvMagneticlvResonancelvSpectroscopy
Chapterlv13lvRadicallvReactions
Chapterlv14lvConjugation,lvResonance,lvandlvDienes
Chapterlv15lvBenzenelvandlvAromaticlvCompounds
Chapterlv16lvReactionslvoflvAromaticlvCompounds
Chapterlv17lvIntroductionlvtolvCarbonyllvChemistry:lvOrganometalliclvReagents;lvOx
idationlvandlvReduction
Chapterlv18lvAldehydeslvandlvKetones—NucleophiliclvAddition
Chapterlv19lvCarboxyliclvAcidslvandlvNitriles
Chapterlv20lvCarboxyliclvAcidslvandlvTheirlvDerivatives-
lvNucleophiliclvAcyllvSubstitution
Chapterlv21lvSubstitutionlvReactionslvoflvCarbonyllvCompoundslvatlvthelvα-Carbon
Chapterlv22lvCarbonyllvCondensationlvReactions
Chapterlv23lvAmines
Chapterlv24lvCarbon-CarbonlvBond-ForminglvReactionslvinlvOrganiclvSynthesis
Chapterlv25lvPericycliclvReactions
Chapterlv26lvCarbohydrates
Chapterlv27lvAminolvAcidslvandlvProteins
Chapterlv28lvSyntheticlvPolymers
Chapterlv29lvLipidslv(Availablelvonline)
Pagelv2
, Chapter 1: Structure and Bonding
lv lv lv lv
1. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvcarbonlvatom?lvA)l v 1s2,lv2s2,lv2p5
B)l v 1s2,lv2s2,lv2p2 C)l v 1s2,lv2s2,lv2p6 D)l v 1s2,lv2s2,lv2p4
2. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvfluorinelvatom?lvA)l v 1s2,lv2s2,lv2p2
B)l v 1s2,lv2s2,lv2p3 C)l v 1s2,lv2s2,lv2p4 D)l v 1s2,lv2s2,lv2p5
3. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvmagnesiumlvcationlv(Mg2+)?vA
l )
2 2 6
1s ,lv2s ,lv2p C) 1s ,lv2s ,lv2p ,lv3s2
2 2 6
B) 1s2,lv2s2,lv2p6,lv3s1 D) 1s2,lv2s2,lv2p6,lv3s2,lv3p2
4. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvchlorinelvanionlv(Cl—)?vA
l )
2 2 6
1s ,lv2s ,lv2p C) 1s ,lv2s ,lv2p6,lv3s2,lv3p5
2 2
B) 1s2,lv2s2,lv2p6,lv3s2,lv3p6 D) 1s2,lv2s2,lv2p6,lv3s2,lv3p4
5. Whichlvoflvthelvfollowinglvstatementslvaboutlvvalencelvelectronslvislvtrue?
A) Theylvarelvthelvmostlvtightlylvheldlvelectrons.
B) Theylvdolvnotlvparticipatelvinlvchemicallvreactions.
Pagelv3
, Chapterlv1:lvStructurelvandlvBondi
ng
C) Theylvarelvthelvoutermostlvelectrons.
D) Theylvreveallvthelvperiodlvnumberlvoflvalvsecond-rowlvelement.
6. Whichlvoflvthelvfollowinglvstatementslvaboutlvbondinglvislvtrue?
A) Covalentlvbondslvresultlvfromlvthelvtransferlvoflvelectronslvfromlvonelvelementlvtolvanother.
B) Ioniclvbondslvresultlvfromlvthelvtransferlvoflvelectronslvfromlvalvmetallvtolvalvnon-metal.
C) Ioniclvbondslvresultlvfromlvthelvsharinglvoflvelectronslvbetweenlvtwolvnon-metals.
D) Covalentlvbondslvresultlvfromlvthelvsharinglvoflvelectronslvbetweenlvtwolvmetals.
7. Whichlvoflvthelvfollowinglvwouldlvyoulvexpectlvtolvhavelvioniclvbonds?
A) CO B)l v FBr C)l v NF3 D)l v NaCl
8. Whichlvoflvthelvfollowinglvmoleculeslvhaslvnonpolarlvcovalentlvbonds?
A) HCl B)l v N2 C)l v CHCl3 D)l v NO
9. Whichlvoflvthelvfollowinglvmoleculeslvcontainlvbothlvcovalentlvandlvioniclvbonds?
A) I,lvII B)l v I,lvIV C)l v II,lvIII D)lvII,lvIV
10. Arrangelvthelvfollowinglvbondslvinlvdecreasinglvorderlvoflvioniclvcharacter,lvputtinglvthelv
mostlvioniclvfirst.
A) Ilv>lvIIlv>lvIIIlv>lvIV C) IVlv>lvIIIlv>lvIIlv>lvI
B) IVlv>lvIIlv>lvIlv>lvIII D) IVlv>lvIIlv>lvIIIlv>lvI
11. Whichlvoflvthelvfollowinglvstatementslvcorrectlylvdescribeslvthelvtypicallvnumberlvoflvbonds
lvforlvcarbon,lvnitrogen,lvandlvoxygen lvinlvmostlvneutral lvorganiclvmolecules?
A) Carbonlvformslv4lvcovalentlvbonds,lvnitrogenlvformslv2lvcovalentlvbondslvandlvoxygenlvf
ormsvl3lvcovalentlvbonds.
B) Carbonlvformslv4lvcovalentlvbonds,lvnitrogenlvformslv3lvcovalentlvbondslvandlvoxygenlvf
ormsvl2lvcovalentlvbonds.
Pagelv4
Smith / All Chapters 1 - 29 / Full Complete
Pagelv1
,Chapterlv1lvStructurelvandlvBonding
Chapterlv2lvAcidslvandlvBases
Chapterlv3lvIntroductionlvtolvOrganiclvMoleculeslvandlvFunctionallvGroups
Chapterlv4lvAlkanes
Chapterlv5lvStereochemistry
Chapterlv6lvUnderstandinglvOrganiclvReactions
Chapterlv7lvAlkyllvHalideslvandlvNucleophiliclvSubstitution
Chapterlv8lvAlkyllvHalideslvandlvEliminationlvReactions
Chapterlv9lvAlcohols,lvEthers,lvandlvRelatedlvCompounds
Chapterlv10lvAlkeneslvandlvAdditionlvReactions
Chapterlv11lvAlkyneslvandlvSynthesis
Chapterlv12lvOxidationlvandlvReduction
SpectroscopylvAlvMasslvSpectrometry
SpectroscopylvBlvInfraredlvSpectroscopy
SpectroscopylvClvNuclearlvMagneticlvResonancelvSpectroscopy
Chapterlv13lvRadicallvReactions
Chapterlv14lvConjugation,lvResonance,lvandlvDienes
Chapterlv15lvBenzenelvandlvAromaticlvCompounds
Chapterlv16lvReactionslvoflvAromaticlvCompounds
Chapterlv17lvIntroductionlvtolvCarbonyllvChemistry:lvOrganometalliclvReagents;lvOx
idationlvandlvReduction
Chapterlv18lvAldehydeslvandlvKetones—NucleophiliclvAddition
Chapterlv19lvCarboxyliclvAcidslvandlvNitriles
Chapterlv20lvCarboxyliclvAcidslvandlvTheirlvDerivatives-
lvNucleophiliclvAcyllvSubstitution
Chapterlv21lvSubstitutionlvReactionslvoflvCarbonyllvCompoundslvatlvthelvα-Carbon
Chapterlv22lvCarbonyllvCondensationlvReactions
Chapterlv23lvAmines
Chapterlv24lvCarbon-CarbonlvBond-ForminglvReactionslvinlvOrganiclvSynthesis
Chapterlv25lvPericycliclvReactions
Chapterlv26lvCarbohydrates
Chapterlv27lvAminolvAcidslvandlvProteins
Chapterlv28lvSyntheticlvPolymers
Chapterlv29lvLipidslv(Availablelvonline)
Pagelv2
, Chapter 1: Structure and Bonding
lv lv lv lv
1. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvcarbonlvatom?lvA)l v 1s2,lv2s2,lv2p5
B)l v 1s2,lv2s2,lv2p2 C)l v 1s2,lv2s2,lv2p6 D)l v 1s2,lv2s2,lv2p4
2. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvfluorinelvatom?lvA)l v 1s2,lv2s2,lv2p2
B)l v 1s2,lv2s2,lv2p3 C)l v 1s2,lv2s2,lv2p4 D)l v 1s2,lv2s2,lv2p5
3. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvmagnesiumlvcationlv(Mg2+)?vA
l )
2 2 6
1s ,lv2s ,lv2p C) 1s ,lv2s ,lv2p ,lv3s2
2 2 6
B) 1s2,lv2s2,lv2p6,lv3s1 D) 1s2,lv2s2,lv2p6,lv3s2,lv3p2
4. Whatlvislvthelvground-
statelvelectroniclvconfigurationlvoflvalvchlorinelvanionlv(Cl—)?vA
l )
2 2 6
1s ,lv2s ,lv2p C) 1s ,lv2s ,lv2p6,lv3s2,lv3p5
2 2
B) 1s2,lv2s2,lv2p6,lv3s2,lv3p6 D) 1s2,lv2s2,lv2p6,lv3s2,lv3p4
5. Whichlvoflvthelvfollowinglvstatementslvaboutlvvalencelvelectronslvislvtrue?
A) Theylvarelvthelvmostlvtightlylvheldlvelectrons.
B) Theylvdolvnotlvparticipatelvinlvchemicallvreactions.
Pagelv3
, Chapterlv1:lvStructurelvandlvBondi
ng
C) Theylvarelvthelvoutermostlvelectrons.
D) Theylvreveallvthelvperiodlvnumberlvoflvalvsecond-rowlvelement.
6. Whichlvoflvthelvfollowinglvstatementslvaboutlvbondinglvislvtrue?
A) Covalentlvbondslvresultlvfromlvthelvtransferlvoflvelectronslvfromlvonelvelementlvtolvanother.
B) Ioniclvbondslvresultlvfromlvthelvtransferlvoflvelectronslvfromlvalvmetallvtolvalvnon-metal.
C) Ioniclvbondslvresultlvfromlvthelvsharinglvoflvelectronslvbetweenlvtwolvnon-metals.
D) Covalentlvbondslvresultlvfromlvthelvsharinglvoflvelectronslvbetweenlvtwolvmetals.
7. Whichlvoflvthelvfollowinglvwouldlvyoulvexpectlvtolvhavelvioniclvbonds?
A) CO B)l v FBr C)l v NF3 D)l v NaCl
8. Whichlvoflvthelvfollowinglvmoleculeslvhaslvnonpolarlvcovalentlvbonds?
A) HCl B)l v N2 C)l v CHCl3 D)l v NO
9. Whichlvoflvthelvfollowinglvmoleculeslvcontainlvbothlvcovalentlvandlvioniclvbonds?
A) I,lvII B)l v I,lvIV C)l v II,lvIII D)lvII,lvIV
10. Arrangelvthelvfollowinglvbondslvinlvdecreasinglvorderlvoflvioniclvcharacter,lvputtinglvthelv
mostlvioniclvfirst.
A) Ilv>lvIIlv>lvIIIlv>lvIV C) IVlv>lvIIIlv>lvIIlv>lvI
B) IVlv>lvIIlv>lvIlv>lvIII D) IVlv>lvIIlv>lvIIIlv>lvI
11. Whichlvoflvthelvfollowinglvstatementslvcorrectlylvdescribeslvthelvtypicallvnumberlvoflvbonds
lvforlvcarbon,lvnitrogen,lvandlvoxygen lvinlvmostlvneutral lvorganiclvmolecules?
A) Carbonlvformslv4lvcovalentlvbonds,lvnitrogenlvformslv2lvcovalentlvbondslvandlvoxygenlvf
ormsvl3lvcovalentlvbonds.
B) Carbonlvformslv4lvcovalentlvbonds,lvnitrogenlvformslv3lvcovalentlvbondslvandlvoxygenlvf
ormsvl2lvcovalentlvbonds.
Pagelv4
