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Answers 2025
Initheichromatographyiofitheireactionimixture,iwateriabsorb
edionicelluloseifunctionediasitheistationaryiphase.iWhatiwasi
theiprincipalifactorideterminingitheimigrationiofiindividuali
componentsiinitheisample?
A)iHydrogenibonding
B)iSoluteiconcentration
C)iStationaryiphaseiconcentration
D)iThicknessiofipaperi-iCORRECTiANSWERS-
A)iHydrogenibondingi
TheiansweritoithisiquestioniisiAibecauseitheirelativeiamounti
ofihydrogenibondingitoitheistationaryiphaseiwillidetermineit
heirelativeirateiofimigrationiofitheivariousicomponentsiinith
eisample.
Whatitypeiofifunctionaligroupiisiformediwheniasparticiacidir
eactsiwithianotheriaminoiaciditoiformiaipeptideibond?i
A)iAniamineigroupi
B)iAnialdehydeigroup
C)iAniamideigroup
D)iAicarboxyligroupi-iCORRECTiANSWERS-
C)iAniamideigroup
TheiansweritoithisiquestioniisiCibecauseitheifunctionaligrou
pithatiformsiduringipeptideibondiformationiisiknowniasiania
mideigroup.
Whichiresearchimethodologyiinvolvesitheiextended,isystema
ticiobservationiofiaicompleteisocialienvironment?
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,A)iComparativeimethods
B)iEthnographicimethods
C)iExperimentalimethods
D)iSurveyimethodsi-iCORRECTiANSWERS-
B)iEthnographicimethods
Ethnographicimethodsiareiaccuratelyidescribediinitheiquest
ioniasiinvolvingisystematiciobservationiofiaicompleteisocialie
nvironment.
comparativeimethodsi-iCORRECTiANSWERS-
researchericollectsidataiaboutidifferentisocialigroupsi(egiwo
rking-class;imiddle-classiandiupper-
class)iandithenicomparesioneigroupiwithianotheritoiidentifyi
whatiisievidentiinioneigroupibutinotianother
Whichitermirefersitoiclosedistatusipositionsithatihinderisoci
alimobility?
A)iClassisystems
B)iCasteisystems
C)iEconomicisystems
D)iFinancialisystemsi-iCORRECTiANSWERS-
B)iCasteisystems
TheicorrectiansweriisiB.iCasteisystemsidescribeiclosedistrati
ficationisystemsithatidoinotiallowiforisocialimobility.
Whatiassumptioniisibeingimadeiifiscientistsiconcludeithatias
particiacidiwasiformedibyitheiprebiologicalisynthesisiinitheip
assage?
A)iAsparticiacidiisiunstableiatitemperaturesibelowi150idegre
esiC.i
B)iAlliofitheimaliciacidiunderwentitheidehydrationireactionit
oiformifumaric/maleiciacid.i
C)iCompoundiAiandicyanideiwereiavailableioniprimitiveiEart
h.i
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,D)iTheireactionibetweeniammoniaiandifumariciacidiwasicata
lyzedibyitheipresenceiofiwater.i-iCORRECTiANSWERS-
C)iCompoundiAiandicyanideiwereiavailableioniprimitiveiEart
h.i
heiansweritoithisiquestioniisiCisince,iiniorderiforitheiexperim
entalireactionisequenceitoibeirelevantitoitheiprimordialiform
ationiofiasparticiacid,itheistartingimaterialsiusedi(Compoun
diAiandicyanide)iareiassumeditoihaveibeeniavailable.
Accordingitoitheidevelopedichromatographyiplateishownibel
ow,iwhatiisitheiapproximateiRfivalueiofiasparticiacid?
asparticiacidi=i2
solventifronti=i10i
A)i0.20
B)i0.50
C)i5
D)i10i-iCORRECTiANSWERS-
TheiansweritoithisiquestioniisiAi(0.20)ibecauseiRfiisitheiratioi
ofitheidistanceitravelledibyitheianalyteirelativeitoitheisolventi
frontiduringiaichromatographiciseparation.iAsparticiaciditra
velleditwoiunits,iwhileitheisolventifrontitravellediteniunits,igi
vingianiRfiofi2/10i=i0.20iforiasparticiacid.
WhichiofitheifollowingistatementsidoesiNOTicorrectlyidescri
beitheidehydrationiofimaliciaciditoifumariciacidiandimaleicia
cid?i
A)iTheireactionioccursimostireadilyiwithitertiaryialcohols.i
B)iTheireactioniinvolvesitheilossiofiaiwaterimolecule.i
C)iTheireactionihasiaicarbocationiintermediate.
D)iTheireactioniisistereospecific.i-iCORRECTiANSWERS-
D)iTheireactioniisistereospecific.
TheiansweritoithisiquestioniisiDibecauseitheifactithatibothifu
mariciandimaleiciacidiareiproducedimeansithatitheidehydrat
ioniofimaliciacidiisiNOTistereospecific.
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, Ifi2-pentanolireplacesi1-
pentanoliinitheireactionishowniiniFigurei3i(SN2),itheirateiofi
substitutioniisilessibecause:i
A)itheiC-Oibondiini2-pentanoliisistrongerithanitheiC-
Oibondiini1-pentanol.
B)ithereiisiaicompetingieliminationireactionithatislowsitheir
ateiofisubstitution.
C)ithereiisimoreistericihindranceiatitheioxygeniatomiini2-
pentanolithaniini1-pentanol,imakingiprotonationilessilikely.
D)ithereiisimoreistericihindranceiatithei2-positioniofi2-
pentanolithaniatithei1-positioniofi1-pentanol.i-
iCORRECTiANSWERS-
D)ithereiisimoreistericihindranceiatithei2-positioniofi2-
pentanolithaniatithei1-positioniofi1-pentanol.
TheiansweritoithisiquestioniisiDibecauseitheirateiofisubstitut
ioniofiprotonatedialcoholsiisisubjectitoistericihindrance.iThis
iinhibitsitheiabilityiofinucleophilesitoicollideiwithitheireactin
gielectrophilicicenteriandislowsitheirateiofireaction.
IfiaisolutionicontainingitheicompoundsishowniiniFigurei4,iisi
injectediintoiaigas-
liquidichromatograph,itheifirstipeakiobservediinitheigcitracei
isiattributableitoiwhichicompound?
A)iMethyl-2-butanol
B)iMethyl-2-butene
C)iChloro-2-methylbutane
D)iBromo-2-mehtylbutanei-iCORRECTiANSWERS-B)iMethyl-
2-butene
TheiansweritoithisiquestioniisiBibecausei2-methyl-2-
buteneiwilliexhibititheilowestimoleculariweightiandialsoithei
weakestiintermoleculariforcesiofiattraction.iThisisubstancei
willithereforeimigrateitheifastestiandibeitheifirstipeakiinithei
gasichromatographi(gc)itrace.
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