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Physical Properties of Solutions

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This chapter explores the chemistry of solutions, beginning with the different types of solutions (solid, liquid, gaseous) and the role of the solute and solvent. It explains the concept of solubility, what makes a solution saturated, unsaturated, or supersaturated, and how “like dissolves like” helps predict solubility based on polarity. The notes guide you through the solution process at the molecular level, including the energetic steps of solute-solute, solvent-solvent, and solute-solvent interactions—and whether the overall process is endothermic or exothermic. Special attention is given to intermolecular forces such as ion-dipole, dipole-induced dipole, and dispersion forces, and how these impact dissolving behavior. The chapter also covers essential concentration units—molarity (M), molality (m), mole fraction (χ), and percent by mass—with clear comparisons and guidance on when to use each. Finally, it examines how temperature and pressure affect solubility, including Henry’s Law for gases. These notes combine visual structure, worked examples, and conceptual practice to help you master both qualitative and quantitative aspects of solution chemistry.

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Subido en
23 de junio de 2025
Número de páginas
9
Escrito en
2024/2025
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Notas de lectura
Profesor(es)
Susan michael
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Chapter 13 – Physical Properties of Solutions
Section 13.1 – Types of Solutions
What is a solution?

solvent and one or more
A solution consists of a _________
________.
solutes
What is meant by an aqueous solution? is a solution where the
Solutions can be classified by the amount of solute solvent is
the maximum amount water.
dissoved relative to ___________________
______________________________________________
that can be dissolved
______________________________.
The amount of solute dissolved in a given
Define solubility: volume of a saturated solution.

Explain the difference between a saturated, unsaturated,
and supersaturated solution:
saturated : contains the max amt . . of solute that will dissolve in a solvent at a specific temp.
·
unsaturated : contains less solute than it has the
-
capacity to dissolve
·


supersaturated : contains more solute than is present in a saturated solution (above capacity
Give an example of a gaseous solution:
air-has N2 O2 and CO2 evenly distributed (homogenous
, ,

Give an example of a solid solution:
brass-mixture of copper + zinc
Give an example of a liquid solution:
Saltwater
Section 13.2 – A Molecular View of the Solution
Process
Define solvation: process by which solute molecules are surrounded
by solvent molecules
The ease with which solute molecules are separated from

, one another and surrounded by solvent molecules
depends on the relative strengths of
____________________________,
the solute-solute attractive forces
__________________________________,
the solvent-solvent attractive forces and
__________________________________.
the solute-solvent attractive forces

What are the 4 types of intermolecular forces (either
solute-solute or solvent-solvent) that occur in pure
substances? Dispersion forces present in all substances ,
-




dipole-dipole -

present in
polar molecules , Hydrogen bonding -
H-0 ,
H-N , H-Fonly &
Solute-solvent attractions can exhibit any of the 4 lon-dipole present
- in

ionic substances
intermolecular forces listed above, or they can exhibit ion-
dipole, dipole-induced dipole, or ion-induced dipole forces.
For each of these intermolecular forces, write the definition
and provide an example:
• Ion-dipole: The charge of an ion is attracted to the partial charge on a
polar molecule
EX) NaCl in H20 Dat
• Dipole-induced dipole:The partial charge on a polar molecule induces A


EX)(O2 in H20--re temporary partial charge
nonpolar molecule/atom.
neighboring on a



• Ion-induced dipole:The charge of an ion induces a temporary partial charge
on neighboring nonpolar molecule/atom




In your own words, summarize the 3 distinct steps used to
describe the solution process in Figure 13.3, including
whether each step in endothermic or exothermic:
1 The separation of solute molecules from one another
.




of solvent molecules from one another
.The
C separation
overcome IMF attractions ,
/both of these 2 steps require an input of energy to
so they are both endothermic REMINDER :

mix
. The solvent
3 + solute molecules ·

Endothermic rxn absorbs energy
(this process is exothermic ·
Exothermic oxu releases energy

Is the overall solution process usually endothermic or
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