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SWS3022 Exam 3 Questions and Answers 100% Pass

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SWS3022 Exam 3 Questions and Answers 100% Pass Know the two principal chemical elements in organic chemical compounds - Carbon & Hydrogen (maybe Oxygen) Know the two properties that make certain types of organic chemicals highly water soluble. - Polarity & Electrical Charge Understand basically the impediments to water solubility for non-ionic hydrophobic organic compounds. - a. Solubility: The ease with which substances dissolve in water; the degree to which organic contaminants impact soil and water quality often is related to their water solubility. b. Non-ionic, non-polar organic chemicals do not possess an electrical charge, nor are the polar. So they don't share any compatibility with water. Example: Dioxin Given the relative insolubility of hydrophobic organic compounds, in what type of substances are they soluble and why? - a. These types of chemicals are compatible with carbon-based environments (similar chemically). They are soluble in environments 2Katelyn Whitman, All Rights Reserved © 2025 that are chemically similar to their chemical properties. Carbon-based compounds dissolve more easily in carbon-based solvents. Understand how hydrophobic organic chemicals interact with organic colloids in soils. - a. An organic colloid has a dense carbon, non-polar uncharged center and carboxylic, phenolic, and enolic (charged, polar) moleculres surrounding it. They provide an organic domain/matrix, in which they move into that organic environment because it is much more compatible with them. b. In regards to synthetic organics: chemicals interact with soil organic matter and slow or arrest their movement. i. The lower the water solubility, usually the stronger the interaction, the slower the chemical movement. What is partitioning? - When the chemical will distribute between the organic and aqueous phases.; The organic colloid behaves like an organic solvent. Understand the basic relationship between the water solubility of organic chemicals and the strength of interaction with organic colloids. - Organic chemicals tend to partition into the organic domain/sediments. Examples of this are pesticides, DDT, and Toxaphene. (Persistence). 3Katelyn Whitman, All Rights Reserved © 2025 Understand basically how hydrophobic organic compounds accumulate in organisms. - a. These chemicals are highly hydrophobic, so they don't like to be in aqueous environment; it will accumulate in the fatty tissues of organisms. It will avoid blood. b. The "affinity" for carbon-based environments can lead to bioaccumulation, particularly of poorly water soluble organic contaminants. c. Lipid Tissue in organisms is principally composed of carbon and hydrogen. Triglycerides are the most common. They are the main ingredient of fatty, or adipose tissue, and are stored in fat droplets inside of adipose cells. d. Hydrophobic organic compounds "prefer" the environment of the lipid tissues (lipophilic). e. Despite low levels of organic chemicals in water due to their low water solubility, high amounts can accumulate in the tissues of living or

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SWS 3022
Grado
SWS 3022

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Subido en
18 de enero de 2025
Número de páginas
19
Escrito en
2024/2025
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Examen
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SWS3022 Exam 3 Questions and
Answers 100% Pass


Know the two principal chemical elements in organic chemical compounds - ✔✔Carbon

& Hydrogen (maybe Oxygen)


Know the two properties that make certain types of organic chemicals highly water

soluble. - ✔✔Polarity & Electrical Charge


Understand basically the impediments to water solubility for non-ionic hydrophobic

organic compounds. - ✔✔a. Solubility: The ease with which substances dissolve in

water; the degree to which organic contaminants impact soil and water quality often is

related to their water solubility.


b. Non-ionic, non-polar organic chemicals do not possess an electrical charge, nor are

the polar. So they don't share any compatibility with water. Example: Dioxin


Given the relative insolubility of hydrophobic organic compounds, in what type of

substances are they soluble and why? - ✔✔a. These types of chemicals are compatible

with carbon-based environments (similar chemically). They are soluble in environments




Katelyn Whitman, All Rights Reserved © 2025 1

,that are chemically similar to their chemical properties. Carbon-based compounds

dissolve more easily in carbon-based solvents.


Understand how hydrophobic organic chemicals interact with organic colloids in soils. -

✔✔a. An organic colloid has a dense carbon, non-polar uncharged center and

carboxylic, phenolic, and enolic (charged, polar) moleculres surrounding it. They

provide an organic domain/matrix, in which they move into that organic environment

because it is much more compatible with them.


b. In regards to synthetic organics: chemicals interact with soil organic matter and slow

or arrest their movement.


i. The lower the water solubility, usually the stronger the interaction, the slower the

chemical movement.


What is partitioning? - ✔✔When the chemical will distribute between the organic and

aqueous phases.; The organic colloid behaves like an organic solvent.


Understand the basic relationship between the water solubility of organic chemicals and

the strength of interaction with organic colloids. - ✔✔Organic chemicals tend to

partition into the organic domain/sediments. Examples of this are pesticides, DDT, and

Toxaphene. (Persistence).




Katelyn Whitman, All Rights Reserved © 2025 2

, Understand basically how hydrophobic organic compounds accumulate in organisms. -

✔✔a. These chemicals are highly hydrophobic, so they don't like to be in aqueous

environment; it will accumulate in the fatty tissues of organisms. It will avoid blood.


b. The "affinity" for carbon-based environments can lead to bioaccumulation,

particularly of poorly water soluble organic contaminants.


c. Lipid Tissue in organisms is principally composed of carbon and hydrogen.

Triglycerides are the most common. They are the main ingredient of fatty, or adipose

tissue, and are stored in fat droplets inside of adipose cells.


d. Hydrophobic organic compounds "prefer" the environment of the lipid tissues

(lipophilic).


e. Despite low levels of organic chemicals in water due to their low water solubility,

high amounts can accumulate in the tissues of living organisms.


Understand basically how hydrophobic organic compounds accumulate in surface soils

and aquatic systems allowing them to persist in the environment. - ✔✔a. Move out of

aqueous phases and into that organic colloids/soils. Why we still have issues with DDT

today.


b. Soils as well as sediments in lakes and rivers often accumulate organic matter.




Katelyn Whitman, All Rights Reserved © 2025 3
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