TEST BANK For Organic Chemistry Mechanistic Patterns, 2nd
Edition by Ogilvie, Ackroyd, Verified Chapters 1 - 20, Complete
Newest Version
What reagents are used in dehydration of OH reaction? - ANSWER: H2SO4 and heat
What type of reaction is dehydration? - ANSWER: E1
What reaction will happen with OH, H2SO4, and heat? - ANSWER: dehydration of OH
What reagents are used in enthalpy SN2 reaction? - ANSWER: OH and PCl3 / PBr3
What reaction will happen with OH and PCl3/PBr3 - ANSWER: enthalpy SN2
What type of reaction is enthalpy with PCl3 / PBr3? - ANSWER: SN2
What reagents are used in enthalpy E2 reaction? - ANSWER: OH, POCl3 / POBr3, and
2 equiv. pyridine
What reaction will happen with OH, POCl3 / POBr3, and 2 equiv. pyridine? -
ANSWER: enthalpy E2
What type of reaction is enthalpy with POCl3 / POBr3? - ANSWER: E2
What reagents are used in entropy reaction? - ANSWER: OH, SOCl2, and pyridine
What reaction will happen with OH, SOCl2, and pyridine? - ANSWER: entropy
What type of reaction is entropy? - ANSWER: SN2
What is the formula for PCC? - ANSWER: CrO3Cl
What reagents are used in oxidation with PCC? - ANSWER: OH and CrOCl3
What reaction will happen with OH and CrOCl3? - ANSWER: oxidation and PCC (E2)
What type of reaction is oxidation with PCC? - ANSWER: "E2"
What reagents are used for oxidation with DMP? - ANSWER: OH and DMP
What reaction will happen with OH and DMP? - ANSWER: oxidation and DMP (E2)
What type of reaction is oxidation with DMP? - ANSWER: "E2"
What does DMP look like? - ANSWER: 2 ish rings with iodine bonded to three OAc
, What are the reagents in the jones oxidation? - ANSWER: OH, CrO3, H2SO4, H2O,
and Ac
What reaction will happen with OH, CrO3, H2SO4, and Ac? - ANSWER: jones
oxidation
What are the two useful SN2 reactions? - ANSWER: alkyne Nus and ether formation
What is the dehydration reaction product? - ANSWER: trans alkene
What is the enthalpy SN2 reaction product? - ANSWER: same alkene with x
substituted for OH (*inversion of carbon stereocenter)
What is the enthalpy E2 reaction product? - ANSWER: same alkene with elimination
What is the entropy reaction product? - ANSWER: same alkene with Cl substituted
for OH (*inversion of carbon stereocenter)
What is the oxidation and PCC reaction product? - ANSWER: same alkene with
elimination (double bond to O)
SAME PRODUCT AS OXIDATION AND DMP
What is the oxidation and DMP reaction product? - ANSWER: same alkene with
elimination (double bond to O)
SAME PRODUCT AS OXIDATION AND PCC
What is the jones oxidation reaction product? - ANSWER: carboxylic acid (elimination
and double bond to O)
What is the stereochemistry of SN1 alkene reactions? - ANSWER: racemic for both C-
H and C-A
What are the reagents of the H-x addition reaction for a symmetric alkene? -
ANSWER: symmetric H-x and alkene
What are the reagents of the H-x addition reaction for an asymmetric alkene? -
ANSWER: asymmetri alkene and H-x
What reaction will happen with H-x? - ANSWER: H-x addition for alkene / alkyne
What is the regioselectivity of H-x addition to alkenes? Why? - ANSWER: form bond
between x and MOST substituted carbon
Edition by Ogilvie, Ackroyd, Verified Chapters 1 - 20, Complete
Newest Version
What reagents are used in dehydration of OH reaction? - ANSWER: H2SO4 and heat
What type of reaction is dehydration? - ANSWER: E1
What reaction will happen with OH, H2SO4, and heat? - ANSWER: dehydration of OH
What reagents are used in enthalpy SN2 reaction? - ANSWER: OH and PCl3 / PBr3
What reaction will happen with OH and PCl3/PBr3 - ANSWER: enthalpy SN2
What type of reaction is enthalpy with PCl3 / PBr3? - ANSWER: SN2
What reagents are used in enthalpy E2 reaction? - ANSWER: OH, POCl3 / POBr3, and
2 equiv. pyridine
What reaction will happen with OH, POCl3 / POBr3, and 2 equiv. pyridine? -
ANSWER: enthalpy E2
What type of reaction is enthalpy with POCl3 / POBr3? - ANSWER: E2
What reagents are used in entropy reaction? - ANSWER: OH, SOCl2, and pyridine
What reaction will happen with OH, SOCl2, and pyridine? - ANSWER: entropy
What type of reaction is entropy? - ANSWER: SN2
What is the formula for PCC? - ANSWER: CrO3Cl
What reagents are used in oxidation with PCC? - ANSWER: OH and CrOCl3
What reaction will happen with OH and CrOCl3? - ANSWER: oxidation and PCC (E2)
What type of reaction is oxidation with PCC? - ANSWER: "E2"
What reagents are used for oxidation with DMP? - ANSWER: OH and DMP
What reaction will happen with OH and DMP? - ANSWER: oxidation and DMP (E2)
What type of reaction is oxidation with DMP? - ANSWER: "E2"
What does DMP look like? - ANSWER: 2 ish rings with iodine bonded to three OAc
, What are the reagents in the jones oxidation? - ANSWER: OH, CrO3, H2SO4, H2O,
and Ac
What reaction will happen with OH, CrO3, H2SO4, and Ac? - ANSWER: jones
oxidation
What are the two useful SN2 reactions? - ANSWER: alkyne Nus and ether formation
What is the dehydration reaction product? - ANSWER: trans alkene
What is the enthalpy SN2 reaction product? - ANSWER: same alkene with x
substituted for OH (*inversion of carbon stereocenter)
What is the enthalpy E2 reaction product? - ANSWER: same alkene with elimination
What is the entropy reaction product? - ANSWER: same alkene with Cl substituted
for OH (*inversion of carbon stereocenter)
What is the oxidation and PCC reaction product? - ANSWER: same alkene with
elimination (double bond to O)
SAME PRODUCT AS OXIDATION AND DMP
What is the oxidation and DMP reaction product? - ANSWER: same alkene with
elimination (double bond to O)
SAME PRODUCT AS OXIDATION AND PCC
What is the jones oxidation reaction product? - ANSWER: carboxylic acid (elimination
and double bond to O)
What is the stereochemistry of SN1 alkene reactions? - ANSWER: racemic for both C-
H and C-A
What are the reagents of the H-x addition reaction for a symmetric alkene? -
ANSWER: symmetric H-x and alkene
What are the reagents of the H-x addition reaction for an asymmetric alkene? -
ANSWER: asymmetri alkene and H-x
What reaction will happen with H-x? - ANSWER: H-x addition for alkene / alkyne
What is the regioselectivity of H-x addition to alkenes? Why? - ANSWER: form bond
between x and MOST substituted carbon
