Name:
ESTER Organic Synt
30a. 30b.
28.
19.
CARBOXYLIC SODIUM 18.
CARBOXYLATE ALCOHOL
ACID
SALT 14.
15.
29. 19. 17.
16.
HYDROXY
HALIDE
SILVER
26. 20.
MIRROR
25. ALDEHYDE
24. 23. 22. 21.
31. 32. IODOFORM 8. 7.
(CHI3) Pale
ACYL or ACID BRICK RED yellow ppt. 6.
9. 5.
CHLORIDE PRECIPITATE ALKENE
21. 20.
33b. 33a. 3. 4.
KETONE
&c.
22. 23.
BRIGHT
ORANGE DIHAL
SOLID AL
38.
NITRILE HYDROXYNITRILE
1° AMIDE 39a.
& b.
12. 11. 10.
2° or 3°
AMIDE HALOGENOALKANE
13.
40.
, 1.
① combustion of alkane '
RTP
C1-1KH } +3202 s
ZC02 + 3h20
② halogenation of an alkane by free radical sub .
" "
9%
CH3 CH3 + ✗ 2 cHzCHzX t HX
initiation
✗2 s 2 ✗ •
hemolytic fission
propagation
•
✗ + CH } CH3 s •
C1-4CH } t HX
•
CH2 CH3 + ✗2 s
CH2X CH3 + •
✗
termination
•
✗ t ◦
X s ✗ 2
•
CHZCH } 1- •
CHZCH } C4H / 0
S
•
CHZCH } + •
✗ S
CH2X CH3
③ halogen ation of alkene by electrophilic addition
HX
•
Hy=ÉH
H
it I H H
/
' '
H H H -
C -
c- It , I
+ s ⊕ '
sit -
C -
C
-
H
gt µ
⊖
H '
I × It
* g-
ESTER Organic Synt
30a. 30b.
28.
19.
CARBOXYLIC SODIUM 18.
CARBOXYLATE ALCOHOL
ACID
SALT 14.
15.
29. 19. 17.
16.
HYDROXY
HALIDE
SILVER
26. 20.
MIRROR
25. ALDEHYDE
24. 23. 22. 21.
31. 32. IODOFORM 8. 7.
(CHI3) Pale
ACYL or ACID BRICK RED yellow ppt. 6.
9. 5.
CHLORIDE PRECIPITATE ALKENE
21. 20.
33b. 33a. 3. 4.
KETONE
&c.
22. 23.
BRIGHT
ORANGE DIHAL
SOLID AL
38.
NITRILE HYDROXYNITRILE
1° AMIDE 39a.
& b.
12. 11. 10.
2° or 3°
AMIDE HALOGENOALKANE
13.
40.
, 1.
① combustion of alkane '
RTP
C1-1KH } +3202 s
ZC02 + 3h20
② halogenation of an alkane by free radical sub .
" "
9%
CH3 CH3 + ✗ 2 cHzCHzX t HX
initiation
✗2 s 2 ✗ •
hemolytic fission
propagation
•
✗ + CH } CH3 s •
C1-4CH } t HX
•
CH2 CH3 + ✗2 s
CH2X CH3 + •
✗
termination
•
✗ t ◦
X s ✗ 2
•
CHZCH } 1- •
CHZCH } C4H / 0
S
•
CHZCH } + •
✗ S
CH2X CH3
③ halogen ation of alkene by electrophilic addition
HX
•
Hy=ÉH
H
it I H H
/
' '
H H H -
C -
c- It , I
+ s ⊕ '
sit -
C -
C
-
H
gt µ
⊖
H '
I × It
* g-
