Nucleophilic
FREE RADICLE SUBSTITUTION MECHANISM
-
Alkane
1) Nuc
1) Initiation ( half curly arrow Tao → homolytic fission)
( 1%1 → Cl .
-111
chlorine radicle
.
+13C -
fission)
2) Propagation Chalfcurly arrow Too → homolytic
B
> first propagation r
"
"
" S "
"←
↳① do
H
f# HCl -1
9¥
-
→ H
+
-
H H
CH } radicle
ii> second
H
propagation
f Mechanisms in AS
H -
drht%c1-H-c-cit.ci
* ↳
,
organic chemistry
( two radicles
3) Termination
join )
→ .cl t.cl → ( Izz
→ ( Hj 1- ( 1. → ( 11-34
→ g. µ , , , , , , ,µ , , , ,
Electrophilic Addition ctullarnw → hetero
lytic fission) Nucleophilic addition (
Alkene carbon
FREE RADICLE SUBSTITUTION MECHANISM
-
Alkane
1) Nuc
1) Initiation ( half curly arrow Tao → homolytic fission)
( 1%1 → Cl .
-111
chlorine radicle
.
+13C -
fission)
2) Propagation Chalfcurly arrow Too → homolytic
B
> first propagation r
"
"
" S "
"←
↳① do
H
f# HCl -1
9¥
-
→ H
+
-
H H
CH } radicle
ii> second
H
propagation
f Mechanisms in AS
H -
drht%c1-H-c-cit.ci
* ↳
,
organic chemistry
( two radicles
3) Termination
join )
→ .cl t.cl → ( Izz
→ ( Hj 1- ( 1. → ( 11-34
→ g. µ , , , , , , ,µ , , , ,
Electrophilic Addition ctullarnw → hetero
lytic fission) Nucleophilic addition (
Alkene carbon
