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Acids and Bases

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Introduction to Acids and Bases

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Week 8 Acids 2 Bases


Arrhenius Theory of Acids and Bases
An arrhenius acid dissociates to produce protons Ht
lb Hd Htcaq t U
cag cage


An arrhenius base dissociates to produce hydroxideions OH I
NaOH caq Nat Caq 1 OH
Caq
flaws not all bases produceOH

ignores the effect of the solvent



Bronsled LowryTheory mostcommon

An acid is a pt donor H2O can be both

A base is a pt acceptor




Proton transfer
curved arrows are used to show e flow as bonds are broken 2 formed in the p transfer

, Acids in chemical Equations
in H2O the proton Ht will bedissociated with at least 1 molecule ofwater to formhydronium ion HzOt
t r
usually H HzOt are used Htmore common 17301 morerealistic

Totheionizationof an acid can be 2 ways

ANOzcap HtCaq 1 NO5 can

HNOzcaq HzOt t NOz caq



Conjugate pairs

conjugateacid base pairs are related through gainlloss of a pt
every acidhas conjugate base a vice versa

NHz t H2O WHY OH
base acid conjacid conj base



Acid 2 Base strength
in acidbase run the favoureddirection of the rain is from thestronger to the weakermember of

the conjugal pair strong acid weak conjugalbase strong base weak conjugate acid



Acid HO in H2O

Strongacids ionize completely in H2O

AN03 H2O HzOt NOT
Weakacids only partially ionize in water

CHzCozH H2O HzOt t CHzCo2



Acid ionization constant
CHzCozIt H2O T HOt t CHzCO2
acid base conj conj
base acid

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