Classification of Metals, Conductors, and Semiconductors
1. Introduction
Materials are classified based on their electrical conductivity into three main categories:
- Metals (Conductors)
- Semiconductors
- Insulators
The ability of a material to conduct electricity depends on the availability of free electrons and the
band structure of the material.
2. Conductors (Metals)
Definition:
Conductors are materials that allow electric current to pass through them easily due to the presence
of free electrons.
Properties of Conductors:
1. High Electrical Conductivity - They have very low electrical resistance.
2. Large Number of Free Electrons - The conduction band is partially filled or overlaps with the
valence band.
3. Low Resistivity (rho) - In the range of 10^-8 to 10^-6 Ohmm.
4. Ohm's Law Obedience - They follow Ohm's Law: V = IR.
5. Temperature Effect - Their resistance increases with temperature.
6. Examples - Copper, Silver, Gold, Aluminum, Iron.
Why Do Metals Conduct Electricity?
In metals, the valence band and conduction band overlap, allowing electrons to move freely, making
them excellent conductors.
3. Semiconductors
Definition:
Semiconductors are materials whose electrical conductivity lies between conductors and insulators.
Their conductivity can be controlled by external factors like temperature and doping.