NCERT Examplar Chemistry Class 12th Resúmenes

The average rate of hydrolysis of butyl chloride depends on factors such as solvent, temperature, and reaction conditions. In aqueous solutions, butyl chloride undergoes hydrolysis via an SN1 mechanism, forming butanol and hydrochloric acid. The reaction rate is influenced by the stability of the carbocation intermediate, with tertiary butyl chloride reacting faster than primary or secondary forms. In polar protic solvents like water or ethanol, the reaction rate increases due to better solvatio...

Chemical kinetics is the study of reaction rates and the factors affecting them. It examines how quickly reactants transform into products and the molecular events involved. Key factors influencing reaction rates include concentration, temperature, catalysts, and surface area. The rate law expresses the relationship between reaction rate and reactant concentrations, while the order of reaction determines how concentration changes impact speed. The Arrhenius equation explains the effect of temper...

Conductivity varies based on factors like temperature, material composition, and impurities. In metals, conductivity typically decreases with increasing temperature due to increased electron scattering. In semiconductors, however, higher temperatures increase conductivity by exciting more charge carriers. In electrolytes, conductivity depends on ion concentration, mobility, and temperature. Higher ion concentration generally increases conductivity, but extreme concentrations can reduce it due to...

A first-order reaction is one where the reaction rate depends linearly on the concentration of a single reactant. The rate law is: text{Rate} = k[A] The integrated rate law for a first-order reaction is: ln[A] = ln[A]_0 - kt where is the rate constant, and is the initial concentration. A plot of ln[A] vs. time gives a straight line with a slope of -k. The half-life () is constant and given by: t_{1/2} = frac{0.693}{k} First-order kinetics are common in radioactive ...

Integrated rate equations describe how reactant concentrations change over time for different reaction orders. Zero-order: (linear decrease, rate independent of concentration). First-order: (exponential decay, rate proportional to concentration). Second-order: (inverse relation, rate proportional to the square of concentration). Each equation helps determine reaction kinetics by analyzing concentration-time data. Half-life () varies with order: constant for first-order, but depe...

Ferromagnetism is a property of materials like iron, cobalt, and nickel, where atomic magnetic moments align in the same direction, creating strong, permanent magnetism. This alignment occurs due to exchange interactions between electrons. Ferromagnetic materials retain their magnetism even after an external magnetic field is removed, making them useful in magnets, transformers, and data storage devices. The magnetization decreases above the Curie temperature, where thermal energy disrupts align...

Electronic configuration describes the arrangement of electrons in an atom's orbitals based on the Aufbau principle, Hund’s rule, and Pauli’s exclusion principle. Electrons fill orbitals in increasing energy order: 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p, and so on. Elements in the same group have similar valence shell configurations, explaining periodic properties. Transition and inner transition elements show exceptions due to stability factors like half-filled and full...

Werner’s theory of coordination compounds, proposed by Alfred Werner in 1893, explains the bonding and structure of complex compounds. It states that metal atoms exhibit two types of valency: primary (oxidation state) and secondary (coordination number). The primary valency is ionizable, while the secondary valency determines the number of ligands attached to the metal. Ligands form coordinate bonds with the central metal ion, creating geometrically distinct structures like octahedral, tetrahe...

The formation of complex compounds involves the coordination of a central metal ion with surrounding ligands through coordinate covalent bonds. These ligands, which can be neutral molecules or anions, donate electron pairs to the metal, forming a stable structure known as a coordination complex. Factors influencing complex formation include the metal’s oxidation state, ligand type, and coordination number. Complex compounds exhibit unique properties like color, magnetism, and catalytic activit...

The frequency factor (A) in the Arrhenius equation (k = A e^(-Ea/RT)) represents the number of times reactant molecules collide with the correct orientation per unit time. It reflects the likelihood of a successful reaction before considering activation energy (Ea). A higher frequency factor indicates more frequent and properly oriented collisions, increasing the reaction rate. Unlike Ea, which depends on energy barriers, A is influenced by molecular size, shape, and reaction mechanism. Though o...

These are the handwritten notes of class 12th chemistry based on the topic of solutions. These notes contains all concept and many important things in few pages.

The CBSE Class 12 Chemistry chapter on d- and f-block elements covers the properties, trends, and applications of transition and inner transition metals. It explains their variable oxidation states, catalytic properties, complex formation, and colored ions due to d-d transitions. The lanthanoids and actinoids show unique electronic configurations and chemical reactivity. Important topics include magnetic properties, alloy formation, and industrial applications (e.g., catalysts, pigments, and sup...

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Lanthanoids (lanthanides) are 14 elements from cerium (Ce) to lutetium (Lu) in the periodic table, following lanthanum (La). They belong to the f-block and have a general electronic configuration of [Xe] 4f¹⁻¹⁴ 5d⁰⁻¹ 6s². Due to the poor shielding of 4f electrons, they exhibit the lanthanoid contraction—a gradual decrease in atomic and ionic sizes across the series. They show variable oxidation states (mainly +3) and have high reactivity, especially with water and acids. Lanthanoid...

Chemical kinetics questions and numericals focus on reaction rates, rate laws, half-life, and activation energy. Common topics include: 1. Rate Law Calculations – Determining reaction order and rate constant () from experimental data. 2. Integrated Rate Equations – Finding concentration over time for zero, first, and second-order reactions. 3. Half-life () – Calculating decay times for different reaction orders. 4. Arrhenius Equation – Finding activation energy () using...

Complex reactions involve multiple steps, consisting of two or more elementary reactions that occur sequentially or in parallel. These reactions often include intermediates, catalysts, and transition states, making their kinetics more intricate than simple reactions. They can be classified as consecutive, parallel, or chain reactions. The overall rate law is determined by the slowest step, known as the rate-determining step. Complex reactions play a crucial role in biochemical pathways, industri...

Colligative properties are properties of solutions that depend only on the number of solute particles, not their identity. These include relative lowering of vapor pressure, boiling point elevation, freezing point depression, and osmotic pressure. They are useful for determining the molar mass of solutes by measuring their effect on a solvent. The relationship between colligative properties and molar mass follows equations like: ΔTf = iKf m (freezing point depression) ΔTb = iKb m (boi...

Materials are classified into metals, semiconductors, and insulators based on their electrical conductivity and band structure. Metals (e.g., copper, silver) have high conductivity due to free electrons in their overlapping valence and conduction bands. Insulators (e.g., rubber, glass) have a wide band gap, preventing electron flow. Semiconductors (e.g., silicon, germanium) have a moderate band gap, allowing controlled conductivity, which increases with temperature or doping. Semiconductors are ...

Coordination compounds consist of a central metal atom or ion surrounded by ligands. Key terms include ligand (molecules/ions donating electron pairs), coordination number (number of ligand attachments to the metal), and coordination sphere (metal-ligand complex). Ligands can be monodentate (one donor atom), bidentate (two donor atoms), or polydentate (multiple donor atoms). The chelate effect stabilizes complexes with polydentate ligands. Oxidation state refers to the metal’s charge. Geometri...

Werner’s theory of coordination compounds, proposed by Alfred Werner in 1893, explains the bonding and structure of complex compounds. It states that metal atoms exhibit two types of valency: primary (oxidation state) and secondary (coordination number). The primary valency is ionizable, while the secondary valency determines the number of ligands attached to the metal. Ligands form coordinate bonds with the central metal ion, creating geometrically distinct structures like octahedral, tetrahe...