TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
Chapter 2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups
Chapter 4 Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions
Chapter 9 Alcohols, Ethers, and Related Compounds
Chapter 10 Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis
Chapter 12 Oxidation and Reduction
Spectroscopy A Mass Spectrometry
Spectroscopy B Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
Chapter 13 Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes
Chapter 15 Benzene and Aromatic Compounds
Chapter 16 Reactions of Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
Chapter 19 Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
Chapter 25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers
Chapter 29 Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding
C) They fare fthe foutermost felectrons.
D) They freveal fthe fperiod fnumber fof fa fsecond-row felement.
6. Which fof fthe ffollowing fstatements fabout fbonding fis ftrue?
A) Covalent fbonds fresult ffrom fthe ftransfer fof felectrons ffrom fone felement fto fanother.
B) Ionic fbonds fresult ffrom fthe ftransfer fof felectrons ffrom fa fmetal fto fa fnon-metal.
C) Ionic fbonds fresult ffrom fthe fsharing fof felectrons fbetween ftwo fnon-metals.
D) Covalent fbonds fresult ffrom fthe fsharing fof felectrons fbetween ftwo fmetals.
7. Which fof fthe ffollowing fwould fyou fexpect fto fhave fionic fbonds?
A) CO B) f FBr C) f NF3 D) f NaCl
8. Which fof fthe ffollowing fmolecules fhas fnonpolar fcovalent fbonds?
A) HCl B) f N2 C) f CHCl3 D) f NO
9. Which fof fthe ffollowing fmolecules fcontain fboth fcovalent fand fionic fbonds?
A) I, fII B) f I, fIV C) f II, fIII D) fII, fIV
10. Arrange fthe ffollowing fbonds fin fdecreasing forder fof fionic fcharacter, fputting fthe
fmostfionic ffirst.
A) I f> fII f> fIII f> fIV C) IV f> fIII f> fII f> fI
B) IV f> fII f> fI f> fIII D) IV f> fII f> fIII f> fI
11. Which fof fthe ffollowing fstatements fcorrectly fdescribes fthe ftypical fnumber fof fbonds
fforfcarbon, fnitrogen, fand foxygen fin fmost fneutral forganic fmolecules?
A) Carbon fforms f4 fcovalent fbonds, fnitrogen fforms f2 fcovalent fbonds fand foxygen
fformsf3 fcovalent fbonds.
B) Carbon fforms f4 fcovalent fbonds, fnitrogen fforms f3 fcovalent fbonds fand foxygen
fformsf2 fcovalent fbonds.
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Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
Chapter 2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups
Chapter 4 Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions
Chapter 9 Alcohols, Ethers, and Related Compounds
Chapter 10 Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis
Chapter 12 Oxidation and Reduction
Spectroscopy A Mass Spectrometry
Spectroscopy B Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
Chapter 13 Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes
Chapter 15 Benzene and Aromatic Compounds
Chapter 16 Reactions of Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
Chapter 19 Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
Chapter 25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers
Chapter 29 Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding
C) They fare fthe foutermost felectrons.
D) They freveal fthe fperiod fnumber fof fa fsecond-row felement.
6. Which fof fthe ffollowing fstatements fabout fbonding fis ftrue?
A) Covalent fbonds fresult ffrom fthe ftransfer fof felectrons ffrom fone felement fto fanother.
B) Ionic fbonds fresult ffrom fthe ftransfer fof felectrons ffrom fa fmetal fto fa fnon-metal.
C) Ionic fbonds fresult ffrom fthe fsharing fof felectrons fbetween ftwo fnon-metals.
D) Covalent fbonds fresult ffrom fthe fsharing fof felectrons fbetween ftwo fmetals.
7. Which fof fthe ffollowing fwould fyou fexpect fto fhave fionic fbonds?
A) CO B) f FBr C) f NF3 D) f NaCl
8. Which fof fthe ffollowing fmolecules fhas fnonpolar fcovalent fbonds?
A) HCl B) f N2 C) f CHCl3 D) f NO
9. Which fof fthe ffollowing fmolecules fcontain fboth fcovalent fand fionic fbonds?
A) I, fII B) f I, fIV C) f II, fIII D) fII, fIV
10. Arrange fthe ffollowing fbonds fin fdecreasing forder fof fionic fcharacter, fputting fthe
fmostfionic ffirst.
A) I f> fII f> fIII f> fIV C) IV f> fIII f> fII f> fI
B) IV f> fII f> fI f> fIII D) IV f> fII f> fIII f> fI
11. Which fof fthe ffollowing fstatements fcorrectly fdescribes fthe ftypical fnumber fof fbonds
fforfcarbon, fnitrogen, fand foxygen fin fmost fneutral forganic fmolecules?
A) Carbon fforms f4 fcovalent fbonds, fnitrogen fforms f2 fcovalent fbonds fand foxygen
fformsf3 fcovalent fbonds.
B) Carbon fforms f4 fcovalent fbonds, fnitrogen fforms f3 fcovalent fbonds fand foxygen
fformsf2 fcovalent fbonds.
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