Deel werkcollege - BLT04 - organische chemie

Werkcollege : organische chemie


1. Functionele groepen en naamgeving
1) Identificer tot welke
functionele groep



1) amine

2) carbonaru


3) aldehyde
4) ester

5) ethen


6) alcohol

7) thiol

8) esten


9)
halogenalkaan
10) ketor

11) niti

12) amida




2) Omcirkel en benoem de
aanwezige functionele groepen



S① ①
*


*
enter

ether

amine
8
*


* alkeen


O * alcohol



3) zijn de namen correct
, gezien hun structuur


a) 6) 5-trimethylpentaan
1-methyl-2-Morylhetaan >
- X 1 ,
4 ,
- X


Che

in
CH-
cr
3
2
Cru-GHz-CHn-
iH
7

in =>
4-ethyloctaan =>
3-methylheptaan
22

ino
1




C) 3-isopropylbutaan - X d) 3-Chloor-3-ethyl-4-broom-4-chloorpentaan 3 X



<Hy 24z CHz CHz C Br
- - -




cr
- --
I



My -C
in
= 2
, 3-dimethylpentaan in
=> 2-broom-2 . 3-dichloor-3-ethylpentaan




1

,4) Gey de structuur

a) 1-broom-3-methylbutaan b) 3 , 3-dichloor-2-methylpentaan (halogunalkaan)
CHz Br CHz C
I I I
I


CHz-CH-CH2-Ce
4

Inalogunatkaan)
CHz-CH-
1




2) 2-broom-3-chloor-3-penteen d) 3-penteer-2-ol Calcohol
-




Br
I
Cl (halogenalkeen) Or
I
(

CHz CH 2 C CH CHz-CH-CH CH-G
-
- = - =


1 1




2) 2-methyl-3-pentun-2-thio - f) 1-methoxy-2-methylbutaan -
(ether) - R-O-R
↳ Ori
CHz (triol( CH3
↓


CHz
CH-C-H = CHz GHz CHz CHg
-
-
- -
0 -



3




g) 2-methoxy-2-methylpropaan 4) Cyclohexylmethyleiner (ether

CH3 Cetrel)

(Hy
3
-


C -
0 -


CHz 0- CHz
ins 1


il N , N-dimethylkeylame Camine) j) N N
, ,
N-trimethylammoniumbromide Cammonium :
NHT
CHs

GHy
-




GHz
-




Ga Ha Ca CHz
- -
- -




N CH-N Br

CHz
k) aceton =

propaan-2-n (hiton) I) 5-methyl-2-nexan (beton

O O CHz
Il Il

CHy
3
-



- CH3 1
CHz 1
-



C GHz
-




CHz
-



C-

m)5-methyl-3-hexeen-2-on -
r) 3 , 3-dimethylbutanal (aldehyde)
8
CHy (beton) O
CHz
in
Il I

443
-




C CH
-
=

CH
-




C
-



G
-




He
-

2-4
ins
6




mierensuur (carbonzuur
O) formaldehyde-methanal
-
-
(1C ! ) pl methaansum
-
=




8 Caldehydel O
Il

H - C -
H n -
c- on
of HCOO




9) 3-hydroxybutaan sus 1)2 -

Chloorpropaan snur


OH O Carbonzuur) 8 U
I Il

-- no--in-gug
1) 3-fenyl-2-proprenzuur -
t) propanoylehloride (zumhalogenidel
8
(carbonzuur) B

on - -
Cu = CH
Il
C
13 C 24z 44g
-


12
- -




O

u)
2-methyl-2-methoxybutaanamide vl ethylmopanat let ar

00-CH3 Camide)
a
-
Il
NH
=-C CHz-CHz-c-o CH2 CHg
- -




wl
methybutaan (ether) X 2-propyl-1-hexaanthiol (thio)

CHz 0
CHz CHz CHz CHg G4y Cz C4z GHz CH
24y SH
- - - - - - -
- - - -




12




i 2

, 2) (Carbonarur)
y) 4-penteen-1-ol (alcohol) 2-methyl-2-butcensuur
or
OCHz
Hz -




CPz -Ge
-




CH
=
CHz
5
on
-k =

cn 44
-




aal
2-ethy propaan letherl bb) 6-amino-4-propylheptaan in (nitril)

0 -


CHz -


CHz NHz CHz
-


CHz -


CHy
↓ I I


CHy CH
CHz & Hz [H-CHz-CH-CPz-CEN
-
- -




CC) 2-ethoxypopaanse (Carbonsuu) dd)
4-methyl-1 2-cyclopentande ,
Carol
5
O
CH ON
Il z 42


H3 CH c on
- - -

32
21

6 -


CHz -



CHy
Or


een 1-broom-4-Methylcycloheraan ff) 1-octun-7-yn (alken <alkyn)
56



CHz4 ↑
Br
He Cz -42 Ce=

Ce -G C
- - -




2
3
(halogenatkaant

gg) 1, 6-octadium (alker nh) azijnenhydride Isumanhydride)
G G
Il Il

Cz
=

CH CM2-Ce = CHz E S c
CHg
- -




ii) 2- butaannitis (nitril jj) 3-mercapto-octaan-1-ol Calcohol)

SH


CHy GHz
- -




Gz CN
-
OH -



(42 CHy
- -


CH -




Ca G4e - GHz Cz G
- - -




kk)
ethylmethylsulfide (sulfidel


CHz-CHz-S- CHz

5)
Geef IVPAC naam



S
6



5
4
31
23
= 2 2
,4 , 4-timethylhexaan
3, 4-dimethylhexaan
4 5
2 3


3
Rent-1-een 1 nex-1-eer-3-yR
j T 6 4 2




6
ethyl-2 3 4 7-
-



. , ,


-234s
tetramethyl
· 4 , 5-dimetrylhex-2-yn 2345678 9
10 decaan




4-ethyl-2-methyl-
Oct-3-un-5-yn 2
3


3-methyl-but-2-o
123"37 8
1
4



2 methylpentaan-3-on
5-methylhept-4-
un-2 3-dive ,
23
U


1
5




5

· Su
3
3, 4-dimethylcyclonex-1-een 4 1
1, 4-dimethylcyclopent
1
3
2 -1 ,
3-dieen
2

6

1 4 Z
3-methylpentaansaus
5 2
3 3 , ,
4
4-tetramethyl,
H 3 5
.
3
nex-1-en-5-yr 1



3