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MCAT CHEM3 Kaplan Review | 100+ Questions | Bond Types, VSEPR, Molecular Geometry, Intermolecular Forces

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This expert-verified Kaplan MCAT CHEM3 document presents 100+ Q&A flashcards designed to master chemical bonding concepts critical for the MCAT Chemical and Physical Foundations section. Ideal for pre-med students, this guide emphasizes key topics such as ionic, covalent, and coordinate bonds, VSEPR theory, bond polarity, and intermolecular forces, supported by equations, examples, and test-style reasoning. Core topics include: Types of bonds: Ionic: electron transfer, crystalline lattice structure, ΔEN > 1.7 Covalent: shared electrons, bond order, formal charge, resonance Coordinate covalent: lone pair donation (e.g., Lewis acid-base interaction) Covalent bond classification: nonpolar (ΔEN < 0.5), polar (ΔEN = 0.5–1.7), and coordinate Bond strength hierarchy: triple > double > single, with shorter bonds being stronger σ and π bonds: formation, geometry, and relative strength VSEPR theory: Electron geometry vs molecular geometry Common shapes: linear, bent, trigonal planar, tetrahedral, trigonal bipyramidal, T-shaped, octahedral Bond angle influence by lone pairs Intermolecular forces: London dispersion (weakest), dipole-dipole, hydrogen bonding Relation to boiling point, solubility, and molecular polarity Formal charge (FC) and its calculation: FC = valence e⁻ – lone pairs – bonding electrons Dipole moment: μ = q × d (charge × distance vector) Lattice energy: strength of ionic compounds based on charge and radius Application examples: Ordering compounds by bond strength or boiling point Drawing Lewis structures, resonance structures, and hybrid orbitals Identifying metalloids and distinguishing network covalent vs molecular compounds Real MCAT-style analogies and mnemonics (e.g., “kidnapping analogy” for ionization energy) Perfect for students in: MCAT prep (Kaplan, AAMC practice tests) General Chemistry Chemical Bonding and Structure courses Inorganic or Physical Chemistry foundational modules Keywords: chemical bonding, ionic bond, covalent bond, coordinate covalent, bond polarity, resonance, bond order, sigma bond, pi bond, formal charge, dipole moment, VSEPR, molecular geometry, bond angles, hybridization, London dispersion, hydrogen bonding, ionization energy, electronegativity, lattice energy, Lewis structure, periodic trends, MCAT chemistry, Kaplan CHEM3

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Uploaded on
December 21, 2025
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MCAT Kaplan Chem3 Bonding 2025
Expert Verified | Ace the Test



Bonding: - 🧠ANSWER ✔✔■ covalent or ionic (higher mpt)


■ octet rule= elements bound to become stable (8ve)

■ stable full non-octets (H,He,Li,Be,B, semi-full transition metals)

■ expanded octet rule= elements that can fit more than 8ve are also stable

(N=3 or greater)


3 bond types: - 🧠ANSWER ✔✔1. ionic=gain/lose ve


2. covalent=shared ve

3. coordinate covalent=one sided 2e contribution to form bond

,Ionic bonds: - 🧠ANSWER ✔✔-transfer of ve from element with low IE→high

IE (metals to halogens)

-between elements of large ΔEN>1.7 (metal to nonmetals)

-electrostatic attraction btn ions (after exchange) keeps bond close

-forms crystalline lattices (high mpt)

-vulnerable to shifts caused by polar solvent (Na and snow)


Covalent bonds: - 🧠ANSWER ✔✔■ sharing of ve btn elements of similar

EN

■ increase bond order (-,=,≡) will increase ↑strength, ↑energy, but has

↓distance

■ Formal changes=due to more/fewer ve after bonding




*resonance occurs in pi bonds (which electrons can alternate btn the 2

bonds)


3 type of covalent bonds: - 🧠ANSWER ✔✔■ nonpolar=balanced EN btn

atoms (ΔEN<0.5)

, ■ polar=unbalanced EN btn atoms (ΔEN=0.5-1.7)




■ coordinate covalent bonds=single atom contributes 2ve into bond(Lewis

acid bases)


Valence shell electron pair repulsion theory (VSEPRT): - 🧠ANSWER ✔✔-

predicts 3D geometry based on e- to e- repulsion

-lone pairs contribute more to angles (push closer to nucleus)

-electronic geometry=position of all (e-)

-molecular geometry=position of bonding pairs only




*when electron domain= you count lone pairs as groups, bonded pairs are

another group


Polarity of molecules: - 🧠ANSWER ✔✔■ depends on sum of dipole

moments (unbalance or not)

■ σ bonds=single head to head overlap (direct)


■ π bonds=overlap of parallel electron clouds (side) in addition to single σ

bond


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