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Inorganic Chemistry Summary RUG

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This summary of Inorganic Chemistry is based on lecture notes, slides and the book Inorganic Chemistry by Mark Weller, Tina Overton, Jonathan Rourke & Fraser Armstrong (7th edition). The order of the chapters is based on the lectures given. Chapter 1: Atomic Structure Chapter 2: Molecular structure and bonding Chapter 3: Molecular symmetry Chapter 4: Structure of solids Chapter 5: Lewis Acids and Bases Chapter 7: Coordination compounds Chapter 20: d-metal complexes: electronic structure and properties

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1 t/m 5, 7 & 20
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Inorganic Chemistry Summary 2024
University of Groningen
Lecturers: Dr. J. Klein and Prof. Dr. E. Otten

,Preface
This summary is based on lecture notes, slides and the book Inorganic Chemistry by Mark
Weller, Tina Overton, Jonathan Rourke & Fraser Armstrong (7th edition). The order of the
chapters is based on the order of the lectures given.

,Table of Content
Chapter 1: Atomic Structure 4
Chapter 2: Molecular structure and bonding 9
Chapter 4: Structure of solids 22
Chapter 5: Lewis Acids and Bases 28
Chapter 3: Molecular symmetry 35
Chapter 7: Coordination compounds 45
Chapter 20: d-metal complexes: electronic structure and properties 51

, Chapter 1: Atomic Structure
Ch1. Atomic Structure

● Quantum numbers and the atomic orbitals that are described by these quantum numbers, with
their (relative) energy.
● Explanation of the trends in the Periodic Table (ionisation energy, atomic/ionic radius,
electronegativity) based on electron configurations and penetration/shielding.




Figure 1: properties elements periodic table

Electron behaves like a particle and like waves.
Schrödinger equation: 𝐻 Ψ = 𝐸Ψ
2 2
𝐸Ψ =− ћ/2𝑚𝑒 𝑑 Ψ/𝑑𝑥 + 𝑉(𝑥) Ψ

V: Potential energy (PE), me: mass electron ћ = ℎ/2π

> Solution only exists for certain values of E.
→ quantization of energies that possess certain discrete
energies in an atom.
R185,43
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