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FALL 2025-CHEM 2273-Organic Chemistry I-Unit 3 Complete Study Guide Organic Compounds Alkanes and their Stereochemistry Klein & Starkey, Organic Chemistry: 5th Edn.

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FALL 2025-CHEM 2273-Organic Chemistry I-Unit 3 Complete Study Guide Organic Compounds Alkanes and their Stereochemistry Klein & Starkey, Organic Chemistry: 5th Edn. Wiley Chapters 4.1-4.8. Skillbuilders: 4.1-4.8. Practice Problems: 4.38-4.42, 4.45, 4.47, 4.53, 4.55-4.58, 4.60, 4.62-4.65, 4.67-4.69, 4.75, 4.76, 4.81. Starting with Functional Groups These are groups of atoms that have chemical behaviour. • The group reacts • Usually reacts of the rest of the molecule. • e.g., double bonds Hydrocarbon Functional Groups Alternating C–C and C=C bonds Functional Groups with a C–X* Bond * X is an electronegative element Alkyl halide Alcohol Ether Phosphate Amine Thiol Sulfide Disulfide Functional Groups Containing a Carbonyl General Structure of Alkanes Alkanes are compounds with and single bonds. • These can be or . • At times described as or . The structural formula for alkanes with no rings present must be: Recall Condensed Structural Diagrams Remember that condensed structures do not show bonds, only . • e.g., butane: 

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FALL 2025-CHEM 2273-Organic
Chemistry I-Unit 3 Complete Study
Guide

Organic Compounds
Alkanes and their Stereochemistry
Klein & Starkey, Organic Chemistry: 5th Edn. Wiley Chapters 4.1-
4.8.

Skillbuilders: 4.1-4.8.

Practice Problems: 4.38-4.42, 4.45, 4.47, 4.53, 4.55-4.58, 4.60,
4.62-4.65, 4.67-4.69, 4.75, 4.76, 4.81.

,Starting with Functional Groups

These are groups of atoms that have chemical behaviour.
• The group reacts
• Usually reacts of the rest of the molecule.


• e.g., double bonds


cholesterol
Br2

CH2Cl2

HO HO
Br
Br




Hydrocarbon Functional Groups

, Double bond Triple bond

Alternating C–C and C=C bonds

Functional Groups with a C–X* Bond

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