Answers to Student Exercises for Spectrometric Identification of Organic Compounds, 8th Edition

All 8 Chapters Covered




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Spectrometric
ldentification of
Organic Compounds

,Answers for Student Exercises 1 .1 to 1 .5 1
Atom Type # of Atoms Mass Total Mass
Hydrogen 22 1.00783 22.17226
a
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-ethyloctane Oxygen 0 15.9949 0.00000
C10H22 Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 0 Exact Mass 142.17226

- (C2Hs•) +


[ r Rule 3
..
[ r - (CH 2 =CH2) +
+



Rule 9

b Atom Type # of Atoms Mass Total Mass
Hydrogen 18 1.00783 18.14094
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-butylcyclohex-1-ene Oxygen 0 15.9949 0.00000
C10H18 Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 2 Exact Mass 138.14094




[
[
rr or



- (C4H9 )
•
Rule 5 and 6
.. 0


r .-.
r r
Rule 6
-
- (CH)=CH 7)


[
r.. r - (C3H7•) \_)/ .. • \ /

,Answers for Student Exercises 1 .1 to 1 .5 + 2
+
Rule 3

, Answers for Student Exercises 1 .1 to 1 .5 3

0 Atom Type # of Atoms Mass Total Mass
Hydrogen 18 18.14094
1.00783 156.00000
c Carbon 13 12.00000 0.00000
2-methyl-1-phenylhexan- l-one Nitrogen 0 14.0031 15.99490
C13H1sO Oxygen 1 15.9949 0.00000
CnHmXxNyOz IHD Sulfur 0 31.9721 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 5 Bromine 78.9183
0 Exact Mass 190.13584




o+
Rule 8

+ +


Rule 9 \=I rH
. ---
\=I
H
/


- (CO) +

Rule 8+9 O I


Atom Type # of Atoms Mass Total Mass
d Hydrogen 22 1.00783 22.17226
Carbon 11 12.00000 132.00000
(E)-undec-3-ene
C11H22
Nitrogen 0 14.0031 0.00000
Oxygen 0 15.9949 0.00000
Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 1 Exact Mass 154.17226



+
+



[ (;
.
•
3
..
r -Rule
(CH5 )


•
+



. ..
r
C5H13)
-(
0 +
Rule 5 +




- (C7H14) +
Rule 9